Telomerization of Butadiene with L-Arabinose and D-Xylose in DMF: Selective Formation of their Monooctadienyl Glycosides
作者： Boris Estrine , Sandrine Bouquillon , Françoise Hénin , Jacques Muzart
关键词: Grafting 、 Organic chemistry 、 Glycoside 、 Polymer chemistry 、 Telomerization 、 Xylose 、 Chemistry 、 Anomer 、 Catalysis 、 Solvent 、 Substrate (chemistry)
摘要: Conditions to achieve the palladium-catalysed telomerization of butadiene with L-arabinose and D-xylose as telogens have been identified. With DMF solvent, optimised ratios substrate, reactants catalytic system allowed selective grafting one octadienyl chain onto anomeric hydroxy group. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
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