Advances in surface-enhanced vibrational spectroscopy at electrochemical interfaces

作者: Andrew J. Wain , Michael A. O’Connell

DOI: 10.1080/23746149.2016.1268931

关键词: Computational chemistryChemistryNanotechnologyInfrared spectroscopyElectrodeRaman scatteringElectrochemistryRaman spectroscopy

摘要: AbstractElectrochemical interfaces are ubiquitous, and characterisation tools that allow us to interrogate them on the molecular scale underpin a wide range of technologies. Because their dynamic nature, in situ or operando measurement is often necessary, coupling electrochemical techniques with spectroscopic methods powerful solution this challenge. Vibrational spectroscopy particular can provide important insights into chemical nature species adsorbed at electrode surfaces. When combined electrochemistry, influence potential perturbation interface be studied, helping build complete picture processes complex systems. Here, we review latest advances vibrational interfaces, focus surface-enhanced approaches including Raman scattering, shell-isolated nanoparticle-enhanced spectroscopy, tip-enhanced infrar...

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