Anisotropy in monocrystalline CVD diamond growth I. A sphere growth experiment

作者: W.J.P. van Enckevort , G. Janssen , L.J. Giling

DOI: 10.1016/0022-0248(91)90035-4

关键词: Lattice constantCondensed matter physicsCrystal growthChemical vapor depositionDiamondCrystalliteEpitaxyOpticsMaterials scienceMaterial properties of diamondMonocrystalline silicon

摘要: Abstract The orientation dependence of diamond growth in a hot filament assisted CVD system has been investigated by epitaxial deposition film on hemispherical, monocrystalline substrate. Two flat faces are encountered, namely {111} and {100}. both is governed steps parallel to . In addition, the {100} covered crystallites random orientation. Apart from some rough regions near {111}, remaining surface sphere relatively smooth. A network cracks close indicates difference lattice parameter between grown layer substrate for this Cathodoluminescence topography hemisphere shows that intensity green blue luminescence thus formation defects varies strongly with direction crystal growth.

参考文章(24)
John Freserick Nye, Physical properties of crystals ,(1985)
P. van der Putte, W.J.P. van Enckevort, L.J. Giling, J. Bloem, Surface morphology of HCl etched silicon wafers Journal of Crystal Growth. ,vol. 43, pp. 659- 675 ,(1978) , 10.1016/0022-0248(78)90145-8
B.V. Spitsyn, L.L. Bouilov, B.V. Derjaguin, Diamond and diamond-like films: Deposition from the vapour phase, structure and properties Progress in Crystal Growth and Characterization. ,vol. 17, pp. 79- 170 ,(1988) , 10.1016/0146-3535(88)90001-9
J.G.E. Gardeniers, W.E.J.R. Maas, R.Z.C. Van Meerten, L.J. Giling, Influence of temperature on the crystal habit of silicon in the SiHCl CVD system I. Experimental results Journal of Crystal Growth. ,vol. 96, pp. 821- 831 ,(1989) , 10.1016/0022-0248(89)90642-8
P. HARTMAN, The non-uniform distribution of faces in a zone Zeitschrift Fur Kristallographie. ,vol. 121, pp. 78- 80 ,(1965) , 10.1524/ZKRI.1965.121.16.78
Seiichiro Matsumoto, Yoichiro Sato, Mutsukazu Kamo, Nobuo Setaka, Vapor Deposition of Diamond Particles from Methane Japanese Journal of Applied Physics. ,vol. 21, pp. L183- L185 ,(1982) , 10.1143/JJAP.21.L183
On Topographically Identifiable Sources of Cathodoluminescence in Natural Diamonds Philosophical Transactions of the Royal Society A. ,vol. 284, pp. 329- 368 ,(1977) , 10.1098/RSTA.1977.0012
W. A. Yarbrough, R. Messier, Current Issues and Problems in the Chemical Vapor Deposition of Diamond Science. ,vol. 247, pp. 688- 696 ,(1990) , 10.1126/SCIENCE.247.4943.688
H. Kawarada, Y. Yokota, Y. Mori, K. Nishimura, A. Hiraki, Cathodoluminescence and electroluminescence of undoped and boron-doped diamond formed by plasma chemical vapor deposition Journal of Applied Physics. ,vol. 67, pp. 983- 989 ,(1990) , 10.1063/1.345708
B.V. Spitsyn, L.L. Bouilov, B.V. Derjaguin, Vapor growth of diamond on diamond and other surfaces Journal of Crystal Growth. ,vol. 52, pp. 219- 226 ,(1981) , 10.1016/0022-0248(81)90197-4