Highly Regioselective Sequential 1,1‐Dihydrosilylation of Terminal Aliphatic Alkynes with Primary Silanes
作者： Zhaoyang Cheng , Shipei Xing , Jun Guo , Biao Cheng , Lan‐Fang Hu
关键词: Stereochemistry 、 Hydrosilylation 、 Regioselectivity 、 Terminal (electronics) 、 Chemistry 、 Silanes 、 Primary (chemistry)
摘要: … Organosilanes are important and valuable compounds, which have been widely used in organic synthesis,[1] materials,[2] biotechnology,[3] and medicinal chemistry,[4] due to their …
sci-hub.se 参考文章(69)
Ian Fleming, Asuncion Barbero, David Walter, Stereochemical Control in Organic-Synthesis Using Silicon-Containing Compounds Chemical Reviews. ,vol. 97, pp. 2063- 2192 ,(1997) , 10.1021/CR941074U
Graeme R. Jones, Yannick Landais, The oxidation of the carbon-silicon bond Tetrahedron. ,vol. 52, pp. 7599- 7662 ,(1996) , 10.1016/S0040-4020(96)00038-5
Chen Cheng, John F. Hartwig, Catalytic Silylation of Unactivated C-H Bonds. Chemical Reviews. ,vol. 115, pp. 8946- 8975 ,(2015) , 10.1021/CR5006414
Jianhui Chen, Tuo Xi, Xiang Ren, Biao Cheng, Jun Guo, Zhan Lu, Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes Organic chemistry frontiers. ,vol. 1, pp. 1306- 1309 ,(2014) , 10.1039/C4QO00295D
Yusuke Kawakami, Yuning Li, Approaches to polymers containing a silicon-oxygen bond in the main chain Designed Monomers and Polymers. ,vol. 3, pp. 399- 419 ,(2000) , 10.1163/156855500750206357
Toyoshi Shimada, Kotaro Mukaide, Akihiro Shinohara, Jin Wook Han, Tamio Hayashi, Asymmetric synthesis of 1-aryl-1,2-ethanediols from arylacetylenes by palladium-catalyzed asymmetric hydrosilylation as a key step. Journal of the American Chemical Society. ,vol. 124, pp. 1584- 1585 ,(2002) , 10.1021/JA017617G
T Mitchell, 1,4-SILYL MIGRATION FROM OXYGEN TO CARBON IN SILYL ALLYL ETHERS : KINETIC AND THERMODYNAMIC FACTORS Tetrahedron. ,vol. 55, pp. 1285- 1294 ,(1999) , 10.1016/S0040-4020(98)01121-1
Hui-Jun Zhang, Daniel L. Priebbenow, Carsten Bolm, Acylsilanes: valuable organosilicon reagents in organic synthesis Chemical Society Reviews. ,vol. 42, pp. 8540- 8571 ,(2013) , 10.1039/C3CS60185D
Anton A. Toutov, Wen-Bo Liu, Kerry N. Betz, Alexey Fedorov, Brian M. Stoltz, Robert H. Grubbs, Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst Nature. ,vol. 518, pp. 80- 84 ,(2015) , 10.1038/NATURE14126
Matthias Driess, Martin Oestreich, New Frontiers and Challenges in Silicon Chemistry:ISOS XVII in Berlin Chemistry: A European Journal. ,vol. 20, pp. 9144- 9145 ,(2014) , 10.1002/CHEM.201404080