Excited-state intramolecular proton transfer in 2,4,5-triarylimidazole molecules

作者: A. I. Shienok , L. S. Kol"tsova , N. L. Zaichenko , V. S. Marevtsev

DOI: 10.1023/A:1021607825803

关键词: LuminescenceChemistryProtonExcited state intramolecular proton transferImidazoleComputational chemistryIntramolecular forceMolecule

摘要: Excited-state intramolecular proton transfer (ESIPT) in the 2,4,5-triarylimidazole molecules was studied by spectral-luminescent technique. For 4,5-diphenyl-(2-hydroxyphenyl)imidazoles, ESIPT occurs both liquid and glassy matrices at 77 K. 4,5-diphenyl-(2-hydroxynaphthyl)imidazole, requires rotation of molecular fragments is not observed

参考文章(9)
Kaustuv Das, Nilmoni Sarkar, Ajit Kumar Ghosh, Devashis Majumdar, Deb Narayan Nath, Kankan Bhattacharyya, Excited-State Intramolecular Proton Transfer in 2-(2-Hydroxyphenyl)benzimidazole and -benzoxazole: Effect of Rotamerism and Hydrogen Bonding The Journal of Physical Chemistry. ,vol. 98, pp. 9126- 9132 ,(1994) , 10.1021/J100088A006
Peter J. Rossky, John D. Simon, Dynamics of chemical processes in polar solvents Nature. ,vol. 370, pp. 263- 269 ,(1994) , 10.1038/370263A0
Norris W. Tyer, Ralph Sherman. Becker, Photochromic spiropyrans. I. Absorption spectra and evaluation of the .pi.-electron orthogonality of the constituent halves Journal of the American Chemical Society. ,vol. 92, pp. 1289- 1294 ,(1970) , 10.1021/JA00708A031
Pi Tai Chou, Marty L. Martinez, John H. Clements, Reversal of excitation behavior of proton-transfer vs. Charge-transfer by dielectric perturbation of electronic manifolds The Journal of Physical Chemistry. ,vol. 97, pp. 2618- 2622 ,(1993) , 10.1021/J100113A024
Pi-Tai Chou, Marty L. Martinez, John H. Clements, The observation of solvent-dependent proton-transfer / charge-transfer lasers from 4' -diethylamino-3-hydroxyflavone Chemical Physics Letters. ,vol. 204, pp. 395- 399 ,(1993) , 10.1016/0009-2614(93)89175-H
Gloria C. Lin, E. S. Awad, M. A. El-Sayed, Temperature and pH dependence of the deprotonation step L550 .fwdarw. M412 in the bacteriorhodopsin photocycle The Journal of Physical Chemistry. ,vol. 95, pp. 10442- 10447 ,(1991) , 10.1021/J100178A035
Guido J. Stueber, Martina Kieninger, Heike Schettler, Wolfgang Busch, Bernd Goeller, Juergen Franke, Horst E. A. Kramer, Helga Hoier, Sonja Henkel, Ultraviolet Stabilizers of the 2-(2'-Hydroxyphenyl)-1,3,5-triazine Class: Structural and Spectroscopic Characterization The Journal of Physical Chemistry. ,vol. 99, pp. 10097- 10109 ,(1995) , 10.1021/J100025A009
Flor Rodríguez-Prieto, J. Carlos Penedo, Manuel Mosquera, Solvent control of molecular structure and excited-state proton-transfer processes of 1-methyl-2-(2′-hydroxyphenyl)- benzimidazole Journal of the Chemical Society, Faraday Transactions. ,vol. 94, pp. 2775- 2782 ,(1998) , 10.1039/A803209B
Jerome F. Hayes, Michael B. Mitchell, Christopher Wicks, A novel synthesis of 2,4,5-triarylimidazoles Heterocycles. ,vol. 38, pp. 575- 585 ,(1994) , 10.3987/COM-93-6595