Two novel Zn(II) coordination polymers based on a carboxylate functionalized imidazophenanthroline derivative ligand
作者： Zhen-Hua Yang , Xian-Feng Xiong , Huai-Ming Hu , Yang Luo , Li-Han Zhang
DOI: 10.1016/J.INOCHE.2011.05.033
关键词: Luminescence 、 Coordination polymer 、 Crystallography 、 Hydrothermal synthesis 、 Derivative (chemistry) 、 Carboxylate 、 Chemistry 、 Ligand 、 Crystal structure 、 Zinc 、 Stereochemistry
摘要: Abstract Two novel zinc(II) coordination polymers, [Zn2(Hcpip)2(ox)]n·2nH2O (1) and [Zn4(Hcpip)2(cpip)2(ox)]n·5nH2O (2), (H2cpip = 2-(2-carboxyphenyl) imidazo [4,5-f]1,10-phenanthroline, H2ox = oxalic acid), have been hydrothermally synthesized characterized by elemental analysis, IR, single crystal X-ray diffraction. Compound 1 is a 1D chain, in which the dinuclear [Zn2(Hcpip)2]2+ units are linked through (ox)2− anions. 2 2D layer structure, constructed from chains bridged These two compounds possess strong luminescence good thermal stabilities.
elsevier.com
sci-hub.se 参考文章(24)
Jian-Qiang Liu, Ya-Nan Zhang, Yao-Yu Wang, Jun-Cheng Jin, Elmira Kh. Lermontova, Qi-Zhen Shi, Interplay of coordinative and supramolecular interactions in formation of a series of metal–organic complexes bearing diverse dimensionalities Dalton Transactions. pp. 5365- 5378 ,(2009) , 10.1039/B822083B
Shin Mizukami, Hirohiko Houjou, Yoshinobu Nagawa, Masatoshi Kanesato, First helical zinc(II) complex with a salen ligand Chemical Communications. ,vol. 3, pp. 1148- 1149 ,(2003) , 10.1039/B301099F
Cristiano Benelli, Dante Gatteschi, Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals. Chemical Reviews. ,vol. 102, pp. 2369- 2388 ,(2002) , 10.1021/CR010303R
Arnd Vogler, Horst Kunkely, Photochemistry of peroxo complexes induced by LMCT, MLCT and peroxide IL/LLCT excitation Coordination Chemistry Reviews. ,vol. 250, pp. 1622- 1626 ,(2006) , 10.1016/J.CCR.2005.10.009
Yongqin Wei, Yunfang Yu, Kechen Wu, Highly Stable Diamondoid Network Coordination Polymer [Mn(NCP)2]n with Notable NLO, Magnetic, and Luminescence Properties Crystal Growth & Design. ,vol. 7, pp. 2262- 2264 ,(2007) , 10.1021/CG070192A
Dong-Rong Xiao, Yang-Guang Li, En-Bo Wang, Lin-Lin Fan, Hai-Yan An, Zhong-Min Su, Lin Xu, Exceptional Self-Penetrating Networks Containing Unprecedented Quintuple-Stranded Molecular Braid, 9-Fold Meso Helices, and 17-Fold Interwoven Helices Inorganic Chemistry. ,vol. 46, pp. 4158- 4166 ,(2007) , 10.1021/IC070054A
Susumu Kitagawa, Ryo Kitaura, Shin-ichiro Noro, Functional Porous Coordination Polymers Angewandte Chemie International Edition. ,vol. 43, pp. 2334- 2375 ,(2004) , 10.1002/ANIE.200300610
Wei Li, Hong-Peng Jia, Zhan-Feng Ju, Jie Zhang, A Novel Chiral Cd(II) Coordination Polymer Based on Achiral Unsymmetrical 3-Amino-1,2,4-triazole with an Unprecedented μ4-Bridging Mode Crystal Growth & Design. ,vol. 6, pp. 2136- 2140 ,(2006) , 10.1021/CG060363W
Jérôme Costa, Robert Ruloff, László Burai, Lothar Helm, André E. Merbach, Rigid MIIL2Gd2III (M = Fe, Ru) complexes of a terpyridine-based heteroditopic chelate: a class of candidates for MRI contrast agents. Journal of the American Chemical Society. ,vol. 127, pp. 5147- 5157 ,(2005) , 10.1021/JA0424169
Yongqin Wei, Kechen Wu, Jiangang He, Wengxu Zheng, Xueying Xiao, A chirally helical coordination polymer self-assembled with the ligand 2-(2-carboxyphenyl)imidazo(4,5-f)(1,10)phenanthroline: crystal structure, SHG response and tunable photoluminescence CrystEngComm. ,vol. 13, pp. 52- 54 ,(2011) , 10.1039/C0CE00547A