A series of lanthanide (III) coordination polymers derived via in situ hydrothermal decarboxylation of quinoline-2,3-dicarboxylic acid
作者： Chun-Bo Liu , Qian Li , Xing Wang , Guang-Bo Che , Xing-Jing Zhang
DOI: 10.1016/J.INOCHE.2013.10.050
关键词: Dicarboxylic acid 、 Crystal structure 、 Quinoline 、 Hydrothermal circulation 、 Single crystal 、 Decarboxylation 、 Inorganic chemistry 、 Infrared spectroscopy 、 Chemistry 、 Lanthanide 、 Polymer chemistry
摘要: Abstract A series of one-dimensional coordination polymers assembled from LnNO3 · 6H2O (Ln = Sm(1), Eu(2), Tb(3), La(4), Ce(5), Pr(6), Nd(7), Dy(8)), quinoline-2,3-dicarboxylic acid (2,3-H2qldc) and 1,10-phenanthroline (phen) formulated as [Ln(2,3-qldc)(3-qlc)(phen)]n (3-Hqlc = quinoline-3-carboxylic acid) were obtained under hydrothermal conditions. It is remarkable that in situ decarboxylation was observed during preparing these polymers. Complexes 1–8 characterized by elemental analyses, IR spectroscopy single crystal X-ray diffraction analyses. The thermal stabilities photoluminescence properties complexes have been investigated.
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