Reexamination of Protonic Locations in Hydrogen Molybdenum Bronze, HxMoO3
作者： Kazuo Eda , Noriyuki Sotani , Masakazu Kunitomo , Makoto Kaburagi
关键词: Cluster (physics) 、 Crystal structure 、 NMR spectra database 、 Bronze 、 Physical chemistry 、 Spectral line 、 Inorganic chemistry 、 Molybdenum bronze 、 Phase (matter) 、 Hydrogen 、 Chemistry
摘要: We reexamined the protonic locations in phase of hydrogen molybdenum bronze (H0.26MoO3) with lowest content by lineshape analysis using a computer simulation, which we dealt systems containing more than three protons. NMR spectra were simulated for various models variety arrangements and linear combinations tested whether they could reproduce observed spectra. Spectra six-proton cluster models, suggested H0.33MoO3by Adamset al.(Acta Crystallogr. Sect. B49, 958 (1993)), also simulated. Then, it was that 3- to 5-proton clusters existed bronze.
harvard.edu
elsevier.com
sci-hub.se 参考文章(23)
M. Kunitomo, K. Eda, N. Sotani, M. Kaburagi, Protonic location in hydrogen molybdenum bronzes HxMoO3 as studied by proton NMR lineshape analysis Journal of Solid State Chemistry. ,vol. 99, pp. 395- 403 ,(1992) , 10.1016/0022-4596(92)90328-S
Robert C.T. Slade, Paul R. Hirst, Barbara C. West, Richard C. Ward, Andreas Magerl, Quasielastic neutron scattering investigation of motional processes associated with two dynamic hydrogen populations in the bronze H1.68MoO3 Chemical Physics Letters. ,vol. 155, pp. 305- 312 ,(1989) , 10.1016/0009-2614(89)85330-8
P DICKENS, The crystal structure of D1.7MoO3 by powder neutron diffraction Solid State Ionics. pp. 1294- 1299 ,(1988) , 10.1016/0167-2738(88)90374-8
A. C. Cirillo, L. Ryan, B. C. Gerstein, J. J. Fripiat, Proton NMR in a hydrogen molybdenum bronze Journal of Chemical Physics. ,vol. 73, pp. 3060- 3068 ,(1980) , 10.1063/1.440564
Noriyuki Sotani, Kazuo Eda, Masayasu Sadamatu, Sadao Takagi, Preparation and Characterization of Hydrogen Molybdenum Bronzes, HxMoO3 Bulletin of the Chemical Society of Japan. ,vol. 62, pp. 903- 907 ,(1989) , 10.1246/BCSJ.62.903
A. Cirillo, J.J. Fripiat, Proton mobility in molybdenum bronzes Journal De Physique. ,vol. 39, pp. 247- 255 ,(1978) , 10.1051/JPHYS:01978003903024700
Cl. Ritter, W. Müller-Warmuth, H. W. Spiess, R. Schöllhorn, Quasi‐One‐Dimensional Behaviour of Hydrogen in H0.35MoO3 and H0.33WO3 as Revealed by Proton NMR Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 86, pp. 1101- 1106 ,(1982) , 10.1002/BBPC.198200047
Roger Rousseau, Enric Canadell, Pere Alemany, Donald H. Galván, Roald Hoffmann, Origin of the Metal-to-Insulator Transition in H0.33MoO3 Inorganic Chemistry. ,vol. 36, pp. 4627- 4632 ,(1997) , 10.1021/IC9705296
P.G. Dickens, J.J. Birtill, C.J. Wright, Elastic and inelastic neutron studies of hydrogen molybdenum bronzes Journal of Solid State Chemistry. ,vol. 28, pp. 185- 193 ,(1979) , 10.1016/0022-4596(79)90071-9
G. E. Pake, Nuclear Resonance Absorption in Hydrated Crystals: Fine Structure of the Proton Line The Journal of Chemical Physics. ,vol. 16, pp. 327- 336 ,(1948) , 10.1063/1.1746878