Prediction of solid polycyclic aromatic hydrocarbons solubility in water, with the NRTL-PR model
作者： Joan Escandell , Isabelle Raspo , Evelyne Neau
DOI: 10.1016/J.FLUID.2013.09.009
关键词: Solubility 、 Thermodynamics 、 Non-random two-liquid model 、 Phase (matter) 、 Work (thermodynamics) 、 Fluid phase 、 Chemistry 、 Petroleum 、 Solid solubility 、 High pressure 、 Organic chemistry 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy 、 General Chemical Engineering
摘要: Abstract The accurate prediction of high pressure phase equilibria is crucial for the development and design chemical engineering processes. Among them modeling complex systems, such as petroleum fluids with water, has become more important exploitation reservoirs in extreme conditions. aim this work to explore capability NRTL-PR model predict solubility solid polycyclic aromatic hydrocarbons water. For purpose, we first validate our methodology fluid predictions gas (CO 2 , C H 6 ) mixtures. Finally, consider PAH by fitting group parameters either only on SLE data or both LLE hydrocarbon–water binary systems.
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Véronique Pauchon, Zeini Cissé, Monique Chavret, Jacques Jose, A new apparatus for the dynamic determination of solid compounds solubility in supercritical carbon dioxide: Solubility determination of triphenylmethane Journal of Supercritical Fluids. ,vol. 32, pp. 115- 121 ,(2004) , 10.1016/J.SUPFLU.2004.03.003
T. W. Zerda, B. Wiegand, J. Jonas, FTIR measurements of solubilities of anthracene in supercritical carbon dioxide Journal of Chemical & Engineering Data. ,vol. 31, pp. 274- 277 ,(1986) , 10.1021/JE00045A005
Kamel Khimeche, Paolo Alessi, Ireneo Kikic, Abdallah Dahmani, Solubility of diamines in supercritical carbon dioxide: Experimental determination and correlation Journal of Supercritical Fluids. ,vol. 41, pp. 10- 19 ,(2007) , 10.1016/J.SUPFLU.2006.09.004
Dinesh S. Mishra, Samuel H. Yalkowsky, Ideal solubility of a solid solute: effect of heat capacity assumptions. Pharmaceutical Research. ,vol. 9, pp. 958- 959 ,(1992) , 10.1023/A:1015873521067
Robert D Goodwin, Provisional values for the thermodynamic functions of ethane Unknow. ,(1974) , 10.6028/NBS.IR.74-398
Seiji Sawamura, Pressure dependence of the solubilities of anthracene and phenanthrene in water at 25°C Journal of Solution Chemistry. ,vol. 29, pp. 369- 375 ,(2000) , 10.1023/A:1005158602563
Ralph Tymms, Physical Properties of Chemical Compounds ,(1955)
Somenath Mitra, Juh W. Chen, Dabir S. Viswanath, Solubility and partial molar volumes of heavy aromatic hydrocarbons in super critical carbon dioxide Journal of Chemical & Engineering Data. ,vol. 33, pp. 35- 37 ,(1988) , 10.1021/JE00051A012
S.T. Chung, K.S. Shing, Multiphase behavior of binary and ternary systems of heavy aromatic hydrocarbons with supercritical carbon dioxide Fluid Phase Equilibria. ,vol. 81, pp. 321- 341 ,(1992) , 10.1016/0378-3812(92)85160-A
Steven H. Neau, Gordon L. Flynn, Solid and liquid heat capacities of n-alkyl para-aminobenzoates near the melting point. Pharmaceutical Research. ,vol. 7, pp. 1157- 1162 ,(1990) , 10.1023/A:1015984310068