Cooperative Effect of Adsorbed Cations and Iodide on the Interception of Back Electron Transfer in the Dye Sensitization of Nanocrystalline TiO2

作者: Serge Pelet , Jacques-E. Moser , Michael Grätzel

DOI: 10.1021/JP9934477

关键词: ChemistryIodidePhotochemistryChemical kineticsTriiodideInorganic chemistryFlash photolysisPropylene carbonateTitanium dioxideSurface chargeElectron transfer

摘要: … of the dye is recovered in the submicrosecond time scale. … Total recovery of the initial absorption, though, requires several hundreds … With Li + and Mg 2+ , the total recovery of the dye …

参考文章(26)
Robert J Hunter, None, Introduction to modern colloid science ,(1993)
Mohammad K. Nazeeruddin, Paul Liska, Jacques Moser, Nick Vlachopoulos, Michael Grätzel, Conversion of Light into Electricity with Trinuclear Ruthenium Complexes Adsorbed on Textured TiO2 Films Helvetica Chimica Acta. ,vol. 73, pp. 1788- 1803 ,(1990) , 10.1002/HLCA.19900730624
Christophe J. Barbé, Francine Arendse, Pascal Comte, Marie Jirousek, Frank Lenzmann, Valery Shklover, Michael Grätzel, Nanocrystalline titanium oxide electrodes for photovoltaic applications Journal of the American Ceramic Society. ,vol. 80, pp. 3157- 3171 ,(2005) , 10.1111/J.1151-2916.1997.TB03245.X
Brian O'Regan, Michael Grätzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films Nature. ,vol. 353, pp. 737- 740 ,(1991) , 10.1038/353737A0
Saif A. Haque, Yasuhiro Tachibana, David R. Klug, James R. Durrant, Charge Recombination Kinetics in Dye-Sensitized Nanocrystalline Titanium Dioxide Films under Externally Applied Bias Journal of Physical Chemistry B. ,vol. 102, pp. 1745- 1749 ,(1998) , 10.1021/JP973335K
Bernd Burfeindt, Thomas Hannappel, Winfried Storck, Frank Willig, Measurement of Temperature-Independent Femtosecond Interfacial Electron Transfer from an Anchored Molecular Electron Donor to a Semiconductor as Acceptor The Journal of Physical Chemistry. ,vol. 100, pp. 16463- 16465 ,(1996) , 10.1021/JP9622905
R. D. Shannon, C. T. Prewitt, Effective ionic radii in oxides and fluorides Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 25, pp. 925- 946 ,(1969) , 10.1107/S0567740869003220