Crystallization kinetics of water below 150 K
作者： Wolfgang Hage , Andreas Hallbrucker , Erwin Mayer , G. P. Johari
DOI: 10.1063/1.466468
关键词: Annealing (metallurgy) 、 Crystallization 、 Infrared spectroscopy 、 Transition temperature 、 Kinetics 、 Grain growth 、 Chemistry 、 Fourier transform infrared spectroscopy 、 Metastability 、 Analytical chemistry
摘要: Metastable liquid water, obtained by heating its hyperquenched glassy state above glass→liquid transition temperature, crystallizes to cubic ice. Kinetics of this crystallization has been studied Fourier transform infrared spectroscopy determining the change in spectra stretching vibrations decoupled OD oscillator 3.6 mole % HOD H2O. The kinetics follows equation x=[1−exp(−ktn)] and is diffusion controlled. Annealing at a temperature below alters as grain–growth process begins control early stages crystallization.
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