Iodide [(η5-indenyl)IrI2]n: an effective precursor to (indenyl)iridium sandwich complexes
作者： Alexander A. Chamkin , Anastasiia M. Finogenova , Yulia V. Nelyubina , Julia Laskova , Alexander R. Kudinov
DOI: 10.1016/J.MENCOM.2016.11.010
关键词: Medicinal chemistry 、 Iodide 、 Iridium 、 Durene 、 Photochemistry 、 Hexamethylbenzene 、 Chemistry 、 Mesitylene 、 Benzene
摘要: The reactions of [(η5-indenyl)IrI2]η with CpTl or arenes in the presence AgBF4 afford [(η5-indenyl)IrCp]+ [(η5-indenyl)Ir(arene)]2+ cations (arene = benzene, mesitylene, durene hexamethylbenzene); structures (η5-indenyl)-Ir(C2H4)2 and [(η5-indenyl)IrCp]PF6 were characterized by X-ray diffraction analysis.
elsevier.com
sci-hub.se 参考文章(31)
Dmitry A. Loginov, Alena O. Belova, Anna V. Vologzhanina, Alexander R. Kudinov, Cationic iridacarboranes [3-(arene)-3,1,2-IrC2B9H11]+ and [3-(MeCN)3-3,1,2-IrC2B9H11]+: Synthesis, reactivity, and bonding. Catalysis of oxidative coupling of benzoic acid with alkynes Journal of Organometallic Chemistry. ,vol. 793, pp. 232- 240 ,(2015) , 10.1016/J.JORGANCHEM.2015.01.022
Thomas Foo, Robert G. Bergman, Synthesis and carbon-hydrogen activation reactions of .eta.5-indenyl(trimethylphosphine)iridium alkyl and hydride complexes Organometallics. ,vol. 11, pp. 1801- 1810 ,(1992) , 10.1021/OM00041A013
J. W. Faller, R. H. Crabtree, A. Habib, Control of slippage and conformation in indenyl complexes Organometallics. ,vol. 4, pp. 929- 935 ,(1985) , 10.1021/OM00124A022
Dmitry A. Loginov, Dmitry V. Muratov, Zoya A. Starikova, Pavel V. Petrovskii, Alexander R. Kudinov, The first metallacarborane triple-decker complexes with a bridging borole ligand Journal of Organometallic Chemistry. ,vol. 691, pp. 3646- 3651 ,(2006) , 10.1016/J.JORGANCHEM.2006.05.014
Toshihiko Uto, Masaki Shimizu, Kenji Ueura, Hayato Tsurugi, Tetsuya Satoh, Masahiro Miura, Rhodium-Catalyzed Oxidative Coupling of Triarylmethanols with Internal Alkynes via Successive C-H and C-C Bond Cleavages Journal of Organic Chemistry. ,vol. 73, pp. 298- 300 ,(2008) , 10.1021/JO7022087
D. A. Loginov, D. V. Muratov, Z. A. Starikova, P. V. Petrovskii, A. R. Kudinov, Stacking reactions of the borole complex Cp*Rh(η5-C4H4BPh) with the dicationic fragments [Cp*M]2+ (M = Rh or Ir) Russian Chemical Bulletin. ,vol. 55, pp. 1581- 1584 ,(2006) , 10.1007/S11172-006-0457-Y
Dmitry A. Loginov, Dmitry V. Muratov, Pavel V. Petrovskii, Zoya A. Starikova, Maddalena Corsini, Franco Laschi, Fabrizia de Biani Fabrizi, Piero Zanello, Alexander R. Kudinov, Reactions of the B‐Phenylborole Complex [CpRh(η5‐C4H4BPh)] with Metalloelectrophiles [(ring)M]2+ European Journal of Inorganic Chemistry. ,vol. 2005, pp. 1737- 1746 ,(2005) , 10.1002/EJIC.200400915
Alexander R Kudinov, Dmitry A Loginov, Zoya A Starikova, Pavel V Petrovskii, Dicationic triple-decker complexes with a bridging boratabenzene ligand Journal of Organometallic Chemistry. ,vol. 649, pp. 136- 140 ,(2002) , 10.1016/S0022-328X(02)01109-9
John A. Brinkman, Tam T. Nguyen, John R. Sowa, Trifluoromethyl-substituted indenyl rhodium and iridium complexes are highly selective catalysts for directed hydroboration reactions Organic Letters. ,vol. 2, pp. 981- 983 ,(2000) , 10.1021/OL005653Z
Dmitry A. Loginov, Andrey M. Miloserdov, Zoya A. Starikova, Pavel V. Petrovskii, Alexander R. Kudinov, Reactions of the (cyclooctadiene)iridium complex CpIr(cod) with halogens Mendeleev Communications. ,vol. 22, pp. 192- 193 ,(2012) , 10.1016/J.MENCOM.2012.06.006