Stacking reactions of the borole complex Cp*Rh(η5-C4H4BPh) with the dicationic fragments [Cp*M]2+ (M = Rh or Ir)
作者： D. A. Loginov , D. V. Muratov , Z. A. Starikova , P. V. Petrovskii , A. R. Kudinov
DOI: 10.1007/S11172-006-0457-Y
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摘要: The reaction of the (borole)rhodium iodide complex [(η-C4H4BPh)RhI]4 with Cp*Li afforded sandwich compound Cp*Rh(η-C4H4BPh) (4). reactions 4 solvated complexes [Cp*M(MeNO2)3]2+(BF 4 − )2 gave triple-decker cationic central borole ligand [Cp*Rh(η-η5:η5-C4H4BPh)MCp*]2+(BF (M = Rh (5) or Ir (7)). structure was established by X-ray diffraction.
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