Self‐Organized Nanostructures in Hard Ceramic Coatings

作者: P. H. Mayrhofer , C. Mitterer , H. Clemens

DOI: 10.1002/ADEM.200500154

关键词: TinChemical engineeringMaterials scienceMetallurgySupersaturationThin filmCeramicNanostructureAnnealing (metallurgy)DislocationNitride

摘要: Nanostructures have attracted increasing interest in modern development of hard coatings for wear-resistant applications. In plasma-assisted vapor deposited thin films, nanostructures can evolve during growth or a post-deposition annealing treatment. this review we demonstrate, using TiB 2.4 , TiN-TiB 2 Ti 0.34 Al 0.66 N, and Ti(N,B) as model-coatings, the its influence on mechanical properties ceramic films. For two-dimensional three-dimensional nanostructure, respectively, organizes itself by segregation driven processes. Growth N results formation supersaturated TiN based phase, which tends to decompose into stable constituents via nm-sized domains. As hardness material is determined resistance bond distortion dislocation motion, depend amount constitution obstacles provided, there direct relation between nanostructure.

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