Correlations of Ba1−xSrxTiO3 Materials and Dielectric Properties

作者: Robert Tsu , Hung-Yu Liu , Wei-Yung Hsu , Scott Summerfelt , Katsuhiro Aoki

DOI: 10.1557/PROC-361-275

关键词: Materials scienceThin filmSchottky diodeComposite materialCapacitanceNucleationDielectricGrain sizeMicrostructureLeakage (electronics)

摘要: Thin film barium strontium titanate, Ba 1−x Sr x TiO 3 (BST), has been deposited on Pt bottom electrodes using metal-organic decomposition (MOD). Optimization of BST electric properties, including capacitance density and leakage current, can be achieved by altering the chemical microstructural attribute films. Dielectric properties are strongly dependent processing temperature, thickness, composition, microstructure, which closely correlated with each other. Nucleation temperatures range from 580°C – 650°C depending thicknesses. The composition giving highest dielectric constant is explained in terms microstructure; increases increasing grain size for films this study. Capacitance 50 fF/μ m 2 current at 1.6 V optimizing materials properties. In addition, conduction through Pt/BST/Pt capacitor shown to consist polarization resulting Debye relaxation true attributed Schottky electron emission.

参考文章(7)
Tsuyoshi Horikawa, Noboru Mikami, Tetsuro Makita, Junji Tanimura, Masayuki Kataoka, Kazunao Sato, Masahiro Nunoshita, Dielectric Properties of (Ba, Sr)TiO3Thin Films Deposited by RF Sputtering Japanese Journal of Applied Physics. ,vol. 32, pp. 4126- 4130 ,(1993) , 10.1143/JJAP.32.4126
R. Moazzami, C. Hu, W.H. Shepherd, A ferroelectric DRAM cell for high-density NVRAMs IEEE Electron Device Letters. ,vol. 11, pp. 454- 456 ,(1990) , 10.1109/55.62994
Hideaki Matsuhashi, Satoshi Nishikawa, Optimum Electrode Materials forTa2O5Capacitors for High- and Low-Temperature Processes Japanese Journal of Applied Physics. ,vol. 33, pp. 1293- 1297 ,(1994) , 10.1143/JJAP.33.1293
Kazuhide Abe, Shuichi Komatsu, Dielectric Constant and Leakage Current of Epitaxially Grown and Polycrystalline SrTiO3Thin Films Japanese Journal of Applied Physics. ,vol. 32, pp. 4186- 4189 ,(1993) , 10.1143/JJAP.32.4186
P-Y. Lesaicherre, H. Yamaguchi, T. Sakuma, Y. Miyasaka, M. Yoshida, A. Ishitani, Preparation of SrTiO3 Thin Films by Ecr and Thermal Mocvd MRS Proceedings. ,vol. 310, pp. 487- ,(1993) , 10.1557/PROC-310-487
J. F. Scott, M. Azuma, C. A. Paz de Araujo, L. D. McMillan, M. C. Scott, T. Roberts, Dielectric breakdown in high-ε films for ULSI DRAMs: II. barium-strontium titanate ceramics Integrated Ferroelectrics. ,vol. 4, pp. 61- 84 ,(1994) , 10.1080/10584589408018661
G. Arlt, D. Hennings, G. de With, Dielectric properties of fine‐grained barium titanate ceramics Journal of Applied Physics. ,vol. 58, pp. 1619- 1625 ,(1985) , 10.1063/1.336051