In Situ Quartz Crystal Microbalance and Quadrupole Mass Spectrometry Studies of Atomic Layer Deposition of Aluminum Oxide from Trimethylaluminum and Water

作者: Antti Rahtu , Teemu Alaranta , Mikko Ritala

DOI: 10.1021/LA010103A

关键词: QuadrupoleAtomic layer depositionQuadrupole mass analyzerReaction mechanismAtmospheric temperature rangeQuartz crystal microbalanceKinetic energyAnalytical chemistryMass spectrometryChemistry

摘要: Reaction mechanisms in the atomic layer deposition of Al2O3 from Al(CH3)3 and water were studied with a quartz crystal microbalance at 150−350 °C quadrupole mass spectrometer 150−400 °C. The growth rate was highest 250 At lower temperatures limited due to kinetic reasons higher amount surface −OH groups. About half ligands released during pulse other pulse. reaction temperature had no marked effect on mechanisms, range studied.

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