Synthesis and characterisation of antioxidant‐modified esters of dipentaerythritol as lubricating base oil

作者: Letao Zhang , Guoxing Cai , Yonglei Wang , Wumanjiang Eli

DOI: 10.1002/LS.1183

关键词: Thermogravimetric analysisOrganic chemistryViscosity indexLubricantFlash pointViscosityChemistryBase oilPour pointFourier transform infrared spectroscopy

摘要: In this paper, five antioxidant-modified esters were synthesised through two steps of simple esterification. Antioxidant-modified multi-hydroxyl compound was at the first step, and second step. This kind is useful in many fields, such as lubricating oil cutting compound, because important functions (antioxidant lubricant) same compound. The active antioxidant group attached to these 3-(3,5-di-tert-butyl-4-hydroxy-phenyl)-propionic acid. characterised with Fourier transforminfrared spectroscopy (FTIR) thermogravimetric (TG) analysis. analytical results FTIR demonstrates changes alcoholic hydroxyl carboxyl suggests that synthesis feasible. TG analysis rotating pressure vessel method show has excellent oxidative stability. physical properties base oil, viscosity, viscosity index, pour point flash point, suggested can be used oil. Copyright (C) 2012 John Wiley a Sons, Ltd.

参考文章(15)
Ponnekanti Nagendramma, Savita Kaul, R. P. S. Bisht, Study of synthesised ecofriendly and biodegradable esters: fire resistance and lubricating properties Lubrication Science. ,vol. 22, pp. 103- 110 ,(2010) , 10.1002/LS.108
Hermann Kroke, Karlheinz Koch, Mixed branched and straight chain ester oils ,(1977)
Samuel Evans, Liquid phenolic antioxidants ,(1993)
Vincent James Gatto, Mark Thomas Devlin, Lubricant containing molybdenum compound and secondary diarylamine ,(1996)
B. Kolwzan, S. Gryglewicz, Synthesis and biodegradability of some adipic and sebacic esters Journal of Synthetic Lubrication. ,vol. 20, pp. 99- 107 ,(2003) , 10.1002/JSL.3000200202
Sumittra Duangkaewmanee, Amorn Petsom, Synergistic and antagonistic effects on oxidation stability of antioxidants in a synthetic ester based oil Tribology International. ,vol. 44, pp. 266- 271 ,(2011) , 10.1016/J.TRIBOINT.2010.10.028
Vincent J. Gatto, Hassan Y. Elnagar, William E. Moehle, Emily R. Schneller, Redesigning alkylated diphenylamine antioxidants for modern lubricants Lubrication Science. ,vol. 19, pp. 25- 40 ,(2007) , 10.1002/LS.28
Anders Pettersson, High-performance base fluids for environmentally adapted lubricants Tribology International. ,vol. 40, pp. 638- 645 ,(2007) , 10.1016/J.TRIBOINT.2005.11.016
I. Bigarre, J.-P. Légeron, Antioxidant kinetics in synthetic lubricants field testing Journal of Synthetic Lubrication. ,vol. 4, pp. 203- 218 ,(1987) , 10.1002/JSL.3000040303