Development of a redox polymer based on poly(2-hydroxyethyl methacrylate) for disposable amperometric sensors
作者： Chiara Zanardi , Laura Pigani , Giulio Maccaferri , Micaela Degli Esposti , Paola Fabbri
DOI: 10.1016/J.ELECOM.2015.10.024
关键词: 2-Hydroxyethyl Methacrylate 、 Membrane 、 (Hydroxyethyl)methacrylate 、 Materials science 、 Polymer chemistry 、 Electrocatalyst 、 Chemical engineering 、 Methacrylate 、 Polymerization 、 Ferrocene 、 Polymer
摘要: Abstract Membranes based on poly(2-hydroxyethyl methacrylate), chemically modified with ferrocene functionalities, are proposed as novel coatings for the development of disposable amperometric sensors. They mass-produced an inert support through UV photo-induced polymerization, forming self-standing films that can be transferred electrode surface. Thanks to characteristic functionalized methacrylate matrix rapidly and reversibly swell by incorporation large amounts water, moieties in intimate contact electrolytic solution. activate effective electrocatalytic processes exploited field sensing. The performance coating respect determination hydroquinone benchmark analyte has been tested both a static solution flux cell.
core.ac.uk
sci-hub.se 参考文章(16)
Chiara Zanardi, Fabio Terzi, Renato Seeber, Functional Materials in Amperometric Sensing: Polymeric, Inorganic, and Nanocomposite Materials for Modified Electrodes ,(2014)
Young A Han, Eun Mi Lee, Byung Chul Ji, THE PHYSICAL PROPERTIES OF POLY(2-HYDROXYETHYL METHACRYLATE) COPOLYMER HYDROGELS USED AS INTRAVAGINAL RINGS Chinese Journal of Polymer Science. ,vol. 27, pp. 359- 366 ,(2009) , 10.1142/S025676790900400X
Rosmawani Mohammad, Musa Ahmad, Lee Yook Heng, An Amperometric Biosensor Utilizing a Ferrocene-Mediated Horseradish Peroxidase Reaction for the Determination of Capsaicin (Chili Hotness) Sensors. ,vol. 13, pp. 10014- 10026 ,(2013) , 10.3390/S130810014
Low Sim Bean, Lee Yook Heng, Bohari M. Yamin, Musa Ahmad, Photocurable ferrocene-containing poly(2-hydroxyl ethyl methacrylate) films for mediated amperometric glucose biosensor Thin Solid Films. ,vol. 477, pp. 104- 110 ,(2005) , 10.1016/J.TSF.2004.08.156
Renato Seeber, Laura Pigani, Fabio Terzi, Chiara Zanardi, Amperometric sensing. A melting pot for material, electrochemical, and analytical sciences Electrochimica Acta. ,vol. 179, pp. 350- 363 ,(2015) , 10.1016/J.ELECTACTA.2015.03.074
G. Inzelt, L. Szabo, The effect of the nature and the concentration of counter ions on the electrochemistry of poly(vinylferrocene) polymer film electrodes Electrochimica Acta. ,vol. 31, pp. 1381- 1387 ,(1986) , 10.1016/0013-4686(86)87048-7
Pierre Audebert, Patrick Calas, Geneviève Cerveau, Robert J.P. Corriu, Nathalie Costa, Modified electrodes from organic-inorganic hybrid gels containing ferrocene units covalently bonded inside a silica network Journal of Electroanalytical Chemistry. ,vol. 372, pp. 275- 277 ,(1994) , 10.1016/0022-0728(94)03337-4
S. Lupu, F. Parenti, L. Pigani, R. Seeber, C. Zanardi, Differential Pulse Techniques on Modified Conventional-Size and Microelectrodes. Electroactivity of Poly[4,4′-bis(butylsulfanyl)-2,2′-bithiophene] Coating Towards Dopamine and Ascorbic Acid Oxidation Electroanalysis. ,vol. 15, pp. 715- 725 ,(2003) , 10.1002/ELAN.200390090
Jiaxiong Wang, Maryanne M Collinson, Electrochemical characterization of inorganic∣organic hybrid films prepared from ferrocene modified silanes Journal of Electroanalytical Chemistry. ,vol. 455, pp. 127- 137 ,(1998) , 10.1016/S0022-0728(98)00149-1
Fuat Dursun, Seyda Korkut Ozoner, Ali Demirci, Mesut Gorur, Faruk Yilmaz, Elif Erhan, Vinylferrocene copolymers based biosensors for phenol derivatives Journal of Chemical Technology & Biotechnology. ,vol. 87, pp. 95- 104 ,(2012) , 10.1002/JCTB.2688