Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents.
作者： Takanori Iwasaki , Xin Min , Asuka Fukuoka , Hitoshi Kuniyasu , Nobuaki Kambe
关键词: Regioselectivity 、 Alkyl 、 Medicinal chemistry 、 Nickel 、 Nickel catalyst 、 Alkylation 、 Aryl 、 Organic chemistry 、 Catalysis 、 Chemistry 、 Reagent
摘要: In the presence of a nickel catalyst, 1,3-butadiene undergoes selective dimerization and alkylarylation with alkyl fluorides aryl Grignard reagents to give 1,6-octadienes groups at 3- 8-positions, respectively, by consecutive formation three carbon-carbon bonds. The an anionic complex plays important role in forming C-C bonds fluorides.
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