Chemical heat pump based on dehydrogenation and hydrogenation of i-propanol and acetone

作者: Tae Gyung Kim , Yeong Koo Yeo , Hyung Keun Song

DOI: 10.1002/ER.4440160910

关键词: Endothermic processChemistryAcetoneOrganic chemistryRaney nickelInorganic chemistryExothermic reactionGibbs free energyDehydrogenationHydrogenCatalysis

摘要: … , based on coupled endothermic and exothermic chemical reactions, … In the present study, the endothermic dehydrogenation of i-… In an endothermic dehydrogenation reaction, i-propanol …

参考文章(12)
Gilbert F. Froment, Kenneth B. Bischoff, Juray De Wilde, Chemical Reactor Analysis and Design ,(1979)
Hayao Imamura, Kazunori Nukui, Kazuhiro Yamada, Susumu Tsuchiya, Tetsuo Sakai, The use of hydride-forming rare-earth–cobalt intermetallic compounds in the dehydrogenation of propan-2-ol Journal of the Chemical Society, Faraday Transactions. ,vol. 83, pp. 743- 750 ,(1987) , 10.1039/F19878300743
C.T.H. Stoddart, C. Kemball, The catalytic hydrogenation of acetone on evaporated metallic films Journal of Colloid Science. ,vol. 11, pp. 532- 542 ,(1956) , 10.1016/0095-8522(56)90169-6
Masaru Yamashita, Feng-Yuen Dai, Minoru Suzuki, Yasukazu Saito, Mechanism of 2-propanol dehydrogenation with suspended nikel fine-particle catalyst. Bulletin of the Chemical Society of Japan. ,vol. 64, pp. 628- 634 ,(1991) , 10.1246/BCSJ.64.628
David E. Mears, John E. Benson, Liquid phase dehydrogenation of isopropanol: Heterogeneous catalysis experiment Journal of Chemical Education. ,vol. 43, pp. 325- ,(1966) , 10.1021/ED043P325
Masaru Yamashita, Tokiji Kawamura, Minoru Suzuki, Yasukazu Saito, Characteristics of Suspended Ru/Carbon Catalyst for 2-Propanol Dehydrogenation Applicable to Chemical Heat Pump Bulletin of the Chemical Society of Japan. ,vol. 64, pp. 272- 278 ,(1991) , 10.1246/BCSJ.64.272
S. S. Lokras, P. K. Deshpande, N. R. Kuloor, Catalytic dehydrogenation of 2-propanol to acetone Industrial & Engineering Chemistry Process Design and Development. ,vol. 9, pp. 293- 297 ,(1970) , 10.1021/I260034A022
J KURIACOSE, Conversion of isopropyl alcohol to acetone on irradiated zinc oxide Journal of Catalysis. ,vol. 1, pp. 498- 507 ,(1962) , 10.1016/0021-9517(62)90122-7