Theoretical calculation of nitrogen isotope equilibrium exchange fractionation factors for various NOy molecules

作者: Wendell W. Walters , Greg Michalski

DOI: 10.1016/J.GCA.2015.05.029

关键词: Stable isotope ratioAqueous solutionQuantum chemistryFractionationChemistryNitrogenSolvationIsotopes of nitrogenAnalytical chemistryMolecule

摘要: … 15 N/ 14 N ratios of NO x are preserved when oxidized to NO 3 … , NO 2 , NO 3 , NO 3 − , HNO 3, PAN, N 2 O 5, ClONO 2, nitrite … ↔ NO 2 occurred with N 2 O 4 in the aqueous phase, and …

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