Synthesis and solution properties of phthalocyanines substituted with four crown ethers
作者： E HAMURYUDAN
DOI: 10.1016/J.DYEPIG.2005.01.018
关键词: Coulometry 、 Inorganic chemistry 、 Cyclic voltammetry 、 Polymer chemistry 、 Derivative (chemistry) 、 Crown ether 、 Zinc 、 Phthalonitrile 、 Proton NMR 、 Adduct 、 Chemistry
摘要: Abstract Metal-free and metal phthalocyanines (M = Ni, Zn, Co) substituted with four benzo-15-crown-5 units through oxy-bridges have been synthesized from a new phthalonitrile derivative, 1-{[(benzo-15-crown-5)-4′-yl]oxy}phthalonitrile ( 3 ). The newly prepared compounds characterized by elemental analyses, IR, 1 H NMR, MS UV–Vis spectroscopy. Alkali interactions of the crown ethers on zinc phthalocyaninato 6 ) are shown to form intermolecular adduct. electrochemical properties ZnPc were investigated using cyclic voltammetry controlled potential coulometry.
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