Modified biochar from Moringa seed powder for the removal of diclofenac from aqueous solution
作者： Afrouz Bagheri , Emmanuel Abu-Danso , Jibran Iqbal , Amit Bhatnagar
DOI: 10.1007/S11356-019-06844-X
关键词: Biochar 、 Adsorption 、 Aqueous solution 、 Phosphoric acid 、 Point of zero charge 、 Chemistry 、 Pyrolysis 、 Nuclear chemistry 、 Fourier transform infrared spectroscopy 、 Moringa
摘要: In this study, Moringa seed powder (MSP) was pyrolyzed at 450 °C to synthesize biochar (MSPB) and treated with phosphoric acid (H3PO4) phosphate-modified (MSPB-HPO) as an adsorbent for the removal of diclofenac (Dfc) from aqueous solution. Fourier transform infrared (FTIR) analysis, energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), pH point zero charge (pHpzc) were conducted give more insight into adsorbent’s properties. The SEM analysis showed transformations in surface morphology parent material synthesized materials after thermal treatment. EDS revealed variation elemental composition prior adsorption Dfc ions. FTIR changes peak intensities functional groups involved removal. pHpzc carried by MSPB-HPO different conditions. Isotherm data best matched Sips model, pseudo-second-order model described kinetics. maximum capacity found be 100.876 mg g−1.
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sci-hub.se 参考文章(50)
Xiang Hu, Zhao Cheng, Removal of diclofenac from aqueous solution with multi-walled carbon nanotubes modified by nitric acid Chinese Journal of Chemical Engineering. ,vol. 23, pp. 1551- 1556 ,(2015) , 10.1016/J.CJCHE.2015.06.010
John Coates, Interpretation of Infrared Spectra, A Practical Approach Encyclopedia of Analytical Chemistry. ,(2006) , 10.1002/9780470027318.A5606
Manali Rathod, Soumya Haldar, Shaik Basha, Nanocrystalline cellulose for removal of tetracycline hydrochloride from water via biosorption: Equilibrium, kinetic and thermodynamic studies Ecological Engineering. ,vol. 84, pp. 240- 249 ,(2015) , 10.1016/J.ECOLENG.2015.09.031
Mohammed Matouq, Nina Jildeh, Mohammed Qtaishat, Muna Hindiyeh, Maha Q. Al Syouf, The adsorption kinetics and modeling for heavy metals removal from wastewater by Moringa pods Journal of environmental chemical engineering. ,vol. 3, pp. 775- 784 ,(2015) , 10.1016/J.JECE.2015.03.027
A.Michael Warhurst, Gordon L. McConnachie, Simon J.T. Pollard, Characterisation and applications of activated carbon produced from Moringa oleifera seed husks by single-step steam pyrolysis Water Research. ,vol. 31, pp. 759- 766 ,(1997) , 10.1016/S0043-1354(97)80989-X
Bahman Ramavandi, Treatment of water turbidity and bacteria by using a coagulant extracted from Plantago ovata Water Resources and Industry. ,vol. 6, pp. 36- 50 ,(2014) , 10.1016/J.WRI.2014.07.001
K.Y. Foo, B.H. Hameed, Insights into the modeling of adsorption isotherm systems Chemical Engineering Journal. ,vol. 156, pp. 2- 10 ,(2010) , 10.1016/J.CEJ.2009.09.013
Irving Langmuir, THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM. Journal of the American Chemical Society. ,vol. 40, pp. 1361- 1403 ,(1918) , 10.1021/JA02242A004
Ehsan Daneshvar, Masoud Kousha, Mojtaba Jokar, Negin Koutahzadeh, Eric Guibal, Acidic dye biosorption onto marine brown macroalgae: Isotherms, kinetic and thermodynamic studies Chemical Engineering Journal. ,vol. 204, pp. 225- 234 ,(2012) , 10.1016/J.CEJ.2012.07.090
Omar R. Harvey, Bruce E. Herbert, Li-Jung Kuo, Patrick Louchouarn, Generalized two-dimensional perturbation correlation infrared spectroscopy reveals mechanisms for the development of surface charge and recalcitrance in plant-derived biochars. Environmental Science & Technology. ,vol. 46, pp. 10641- 10650 ,(2012) , 10.1021/ES302971D