Polymerization and Finishing of Tetrafluoroethylene

作者: Sina Ebnesajjad

DOI: 10.1016/B978-1-4557-3199-2.00008-2

关键词: Chemical engineeringPolytetrafluoroethyleneDispersion polymerizationPolymerTetrafluoroethylenePolymerizationPolychlorotrifluoroethylenePolymer chemistryChlorotrifluoroethyleneDispersion (chemistry)Materials science

摘要: Tetrafluoroethylene (TFE) is the main constituent monomer for preparation of polytetrafluoroethylene (PTFE) resins. TFE polymerized in an aqueous suspension medium to produce granular PTFE These polymers are produced by polymerization and addition trace amounts a comonomer modify homopolymers. After completion polymerization, “raw” dispersion particles water obtained, which must be “finished” before commercial application possible. Raw dispersions contain wide range solids, often, <10–45% weight water. Fine powder using coagulation, dispersion, drying processes. High molecular chlorotrifluoroethylene (CTFE) synthesized, characterized, utilized diffusion process polychlorotrifluoroethylene (PCTFE). The synthesis CTFE has been carried out bulk, suspension, emulsion polymerizations.

参考文章(16)
C. A. Sperati, H. W. Starkweather, Fluorine-containing polymers. II. Polytetrafluoroethylene Fortschritte Der Hochpolymeren-Forschung. ,vol. 2, pp. 465- 495 ,(1961) , 10.1007/BFB0050504
Paul J. Flory, Principles of polymer chemistry ,(1953)
Dewey L. Kerbow, Carleton A. Sperati, Physical Constants of Fluoropolymers The Wiley Database of Polymer Properties. ,(1999) , 10.1002/0471532053.BRA026
Frederik Hoornaert, Philippe A.L. Wauters, Gabrie M.H. Meesters, Sotiris E. Pratsinis, Brian Scarlett, Agglomeration behaviour of powders in a Lödige mixer granulator Powder Technology. ,vol. 96, pp. 116- 128 ,(1998) , 10.1016/S0032-5910(97)03364-0
C.U Kim, J.M Lee, S K. Ihm, Emulsion polymerization of tetrafluoroethylene: effects of reaction conditions on particle formation Journal of Fluorine Chemistry. ,vol. 96, pp. 11- 21 ,(1999) , 10.1016/S0022-1139(98)00328-5
B. Améduri, B. Boutevin, G. Kostov, Fluoroelastomers: synthesis, properties and applications Progress in Polymer Science. ,vol. 26, pp. 105- 187 ,(2001) , 10.1016/S0079-6700(00)00044-7
Marie-Pierre Gelin, Bruno Ameduri, Radical solution copolymerisation of vinylidene fluoride with hexafluoropropene Journal of Fluorine Chemistry. ,vol. 126, pp. 575- 583 ,(2005) , 10.1016/J.JFLUCHEM.2004.12.010
Phung K. Le, Paul Avontuur, Michael J. Hounslow, Agba D. Salman, A microscopic study of granulation mechanisms and their effect on granule properties Powder Technology. ,vol. 206, pp. 18- 24 ,(2011) , 10.1016/J.POWTEC.2010.06.014