Ionic diffusion in the double layer at model electrode/molten-salt interfaces

作者: K Tankeshwar , M P Tosi

DOI: 10.1088/0953-8984/3/48/023

关键词: ChemistryIonic bondingElectrodeThermodynamicsElectrochemical cellAnalytical chemistryMolten saltDiffusion (business)Diffusion layerIonic strengthElectrolyte

摘要: The anisotropic ionic diffusion coefficients in model electrochemical cells the molten-salt regime for electrolyte are evaluated from density profiles reported simulation work of Grout and co-workers. A local description processes counter-ions co-ions electrical double layer is obtained data.

参考文章(7)
Robert Zwanzig, On the relation between self‐diffusion and viscosity of liquids The Journal of Chemical Physics. ,vol. 79, pp. 4507- 4508 ,(1983) , 10.1063/1.446338
J. O'M. Bockris, S. R. Richards, L. Nanis, Self-Diffusion and Structure in Molten Group II Chlorides1 Journal of Chemistry. ,vol. 69, pp. 1627- 1637 ,(1965) , 10.1021/J100889A031
Udayan Mohanty, Inferences from a microscopic model for the Stokes-Einstein relation. Physical Review A. ,vol. 32, pp. 3055- 3058 ,(1985) , 10.1103/PHYSREVA.32.3055
K Tankeshwar, B Singla, K N Pathak, A simple model for the calculation of self-diffusion Journal of Physics: Condensed Matter. ,vol. 3, pp. 3173- 3182 ,(1991) , 10.1088/0953-8984/3/18/011
R. M. Esnouf, A. C. D. Smith, P. J. Grout, The computer simulation of the metal-molten salt interface Philosophical Magazine. ,vol. 58, pp. 27- 35 ,(1988) , 10.1080/01418618808205172
K Tankeshwar, M P Tosi, Ionic diffusion in superionic-conductor melts Journal of Physics: Condensed Matter. ,vol. 3, pp. 7511- 7518 ,(1991) , 10.1088/0953-8984/3/38/022