Self-Diffusion and Structure in Molten Group II Chlorides1

摘要: En*/RT) is applicable to all salts exceptZnCl2. For ZnCl2, log D* vs. 1/T exhibited curvature. The data are used to test the degree of applicability of several models for liquids. The heats of activation can be predicted from a version of the hole model. Indications con-cerning structural particles present are deduced from considerations of deviations from the Stokes-Einstein and Nernst-Einstein relationships.