Decomposition pathways of homogeneous catalysts
DOI: 10.1016/S0926-860X(00)00844-9
关键词: Chemical decomposition 、 Polymerization 、 Catalysis 、 Organic chemistry 、 Decomposition 、 Chemistry 、 Hydrocyanation 、 Homogeneous catalysis 、 Carbonylation 、 Hydroformylation 、 Photochemistry
摘要: Homogeneous catalysts can decompose in a variety of ways: metal deposition, ligand decomposition, reaction with impurities, dimer formation, and the center ligand. Sometimes these side reactions lead to temporary deactivation only catalyst activity be restored. Without attempting complete, I have collected range examples decomposition. Our will concentrate on homogeneous commercial interest, such as polymerization, oxidation, oligomerization, hydroformylation, carbonylation, hydrocyanation, cross-coupling reactions.
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