Microwave-assisted modulated synthesis of zirconium-based metal-organic framework (Zr-MOF) for hydrogen storage applications
作者： Jianwei Ren , Tshiamo Segakweng , Henrietta Langmi , Nicholas Musyoka , Brian North
DOI: 10.3139/146.111047
关键词: Materials science 、 Inorganic chemistry 、 Zirconium 、 Microwave assisted 、 Metal-organic framework 、 Hydrogen storage 、 Specific surface area 、 Octahedron
摘要: Abstract Zirconium-based metal–organic framework (Zr-MOF) was synthesized using a microwave-assisted modulated method in short reaction time of 5 min. The Zr-MOF material highly crystalline with well-defined octahedral shaped crystals, and it exhibited comparable hydrogen storage capacity to similar specific surface area conventional methods much longer synthesis time.
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nwu.ac.za参考文章(19)
Jae-Yong Choi, Jeo Kim, Sung-Hwa Jhung, Hye-Kyoung Kim, Jong-San Chang, Hee K Chae, Microwave synthesis of a porous metal-organic framework, zinc terephthalate MOF-5 Bulletin of The Korean Chemical Society. ,vol. 27, pp. 1523- 1524 ,(2006) , 10.5012/BKCS.2006.27.10.1523
J. Rouquerol, P. Llewellyn, F. Rouquerol, Is the bet equation applicable to microporous adsorbents Studies in Surface Science and Catalysis. ,vol. 160, pp. 49- 56 ,(2007) , 10.1016/S0167-2991(07)80008-5
Hailian Li, Mohamed Eddaoudi, M. O'Keeffe, O. M. Yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework Nature. ,vol. 402, pp. 276- 279 ,(1999) , 10.1038/46248
Youn-Sang Bae, A. Özgür Yazaydın, Randall Q. Snurr, Evaluation of the BET Method for Determining Surface Areas of MOFs and Zeolites that Contain Ultra-Micropores Langmuir. ,vol. 26, pp. 5475- 5483 ,(2010) , 10.1021/LA100449Z
Jasmina Hafizovic Cavka, Søren Jakobsen, Unni Olsbye, Nathalie Guillou, Carlo Lamberti, Silvia Bordiga, Karl Petter Lillerud, A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. Journal of the American Chemical Society. ,vol. 130, pp. 13850- 13851 ,(2008) , 10.1021/JA8057953
Hussein Rasool Abid, Huyong Tian, Ha-Ming Ang, Moses O. Tade, Craig E. Buckley, Shaobin Wang, Nanosize Zr-metal organic framework (UiO-66) for hydrogen and carbon dioxide storage Chemical Engineering Journal. ,vol. 187, pp. 415- 420 ,(2012) , 10.1016/J.CEJ.2012.01.104
Jianwei Ren, Henrietta W. Langmi, Brian C. North, Mkhulu Mathe, Dmitri Bessarabov, Modulated synthesis of zirconium-metal organic framework (Zr-MOF) for hydrogen storage applications International Journal of Hydrogen Energy. ,vol. 39, pp. 890- 895 ,(2014) , 10.1016/J.IJHYDENE.2013.10.087
Qingyuan Yang, Andrew D. Wiersum, Philip L. Llewellyn, Vincent Guillerm, Christian Serre, Guillaume Maurin, Functionalizing porous zirconium terephthalate UiO-66(Zr) for natural gas upgrading: a computational exploration Chemical Communications. ,vol. 47, pp. 9603- 9605 ,(2011) , 10.1039/C1CC13543K
Hui Wu, Yong Shen Chua, Vaiva Krungleviciute, Madhusudan Tyagi, Ping Chen, Taner Yildirim, Wei Zhou, Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption Journal of the American Chemical Society. ,vol. 135, pp. 10525- 10532 ,(2013) , 10.1021/JA404514R
Weibin Liang, Deanna M. D'Alessandro, Microwave-assisted solvothermal synthesis of zirconium oxide based metal–organic frameworks Chemical Communications. ,vol. 49, pp. 3706- 3708 ,(2013) , 10.1039/C3CC40368H