Carbonylation of methanol to acetic acid using homogeneous Ru complex catalyst
作者： Ashutosh A. Kelkar , Devidas S. Kolhe , Raghunath V. Chaudhari
DOI: 10.1016/0022-328X(92)80101-3
关键词: Selectivity 、 Chemistry 、 Primary alcohol 、 Carbonylation 、 Medicinal chemistry 、 Organic chemistry 、 Catalysis 、 Carbon monoxide 、 Methanol 、 Acetic acid 、 Hydrogen
摘要: Carbonylation of methanol to give acetic acid catalysed by Ru complexes such as trans-Ru(CO)2Cl2(PPh3)2, cis-Ru(CO)2Cl2(PPh3)2 and H2Ru(CO)(PPh3)3 is reported. The highest activity selectivity were obtained with the catalyst precursor. Hydrogen increases catalysts cis-Ru(CO)2Cl2(PPh3)2, but has no influence on in case H2Ru(CO)(PPh3)3.
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