Enantioselective synthesis of each stereoisomer of the pyranoid linalool oxides: the linalool route
作者： Giovanni Vidari , Anna Di Rosa , Giuseppe Zanoni , Carlo Bicchi
DOI: 10.1016/S0957-4166(99)00359-6
关键词: Tetrahydropyran 、 Allylic alcohol 、 Linalool 、 Stereoselectivity 、 Organic chemistry 、 Dihydroxylation 、 Stereochemistry 、 Enantioselective synthesis 、 Chemistry
摘要: Abstract Each of the four enantiomerically pure tetrahydropyran linalool oxides was prepared by separate enantioselective Sharpless dihydroxylation (R)- or (S)-linalyl acetate with AD-mix-α AD-mix-β, followed a completely stereoselective N-phenylselenophthalimide cyclization an intermediate allylic alcohol.
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