6-Bromo-6-deoxy Hexose Derivatives by Ring Opening of Benzylidene Acetals with N-Bromosuccinimide: Methyl 4-O-Benzoyl-6-bromo-6-deoxy-α-D-Glucopyranoside
作者： S. Hanessian
DOI: 10.1002/0471264180.OS065.30
关键词: Medicinal chemistry 、 Carbon tetrachloride 、 Organic chemistry 、 Chemistry 、 Hexose 、 N-Bromosuccinimide 、 Ring (chemistry) 、 Halogen 、 Halogenation 、 Ether
摘要: 6-Bromo-6-deoxy hexose derivatives by ring opening of benzylidene acetals with N-bromosuccinimide: methyl 4-O-benzoyl-6-bromo-6-deoxy-α-D-glucopyranoside product: Methyl 4-O-benzoyl-6-bromo-6-deoxy-α-D-glucopyranoside reactant: 20.5 g (72.61 mmol) 4,6-O-benzylidene-α-D-glucopyranoside Keywords: halogenation, bromination; oxidation, miscellaneous; replacement reactions, ether halogen; carbon tetrachloride
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