Development of laser diagnostic probes for chemical vapor deposition of InP/InGaAsP epitaxial layers

作者: V. M. Donnelly , R. F. Karlicek

DOI: 10.1063/1.331512

关键词: ImpurityLaserMaterials scienceExcimer laserLayer (electronics)Analytical chemistryEpitaxyChemical vapor depositionSpectroscopyDye laser

摘要: Laser spectroscopic methods have been developed for the detection of PH3, P2, AsH3, As2, InCl, and GaCl, using both tunable‐dye‐laser induced fluorescence excimer laser excitation. These are primary reactants participating in chemical vapor deposition (CVD) InP/InGaAsP epitaxial layers. Using a reaction tube designed to simulate CVD growth reactor, limits measured all these species well below those levels typically employed during layer growth. Specific applications outlined, several examples given relating techniques conditions expected

参考文章(9)
The Analysis of a $^2$A$_1$-$^2$B$_1$ Electronic Band System of the AsH$_2$ and AsD$_2$ Radicals Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 305, pp. 271- 290 ,(1968) , 10.1098/RSPA.1968.0118
G.H. Olsen, T.J. Zamerowski, Crystal growth and properties of binary, ternary and quaternary (In,Ga)(As,P) alloys grown by the hydride vapor phase epitaxy technique Progress in Crystal Growth and Characterization. ,vol. 2, pp. 309- 375 ,(1979) , 10.1016/0146-3535(81)90039-3
Terrill A. Cool, John B. Koffend, Two‐photon excitation of indium atoms by photodissociation of InCI and InBr Journal of Chemical Physics. ,vol. 74, pp. 2287- 2292 ,(1981) , 10.1063/1.441345
C. L. Sam, James T. Yardley, Laser induced production of excited states of PH and PH2 from phosphine Journal of Chemical Physics. ,vol. 69, pp. 4621- 4627 ,(1978) , 10.1063/1.436414
G. Olsen, T. Zamerowski, Vapor-phase growth of (In,Ga)(As,P) quaternary alloys IEEE Journal of Quantum Electronics. ,vol. 17, pp. 128- 138 ,(1981) , 10.1109/JQE.1981.1071080
J. W. T. Spinks, Gerhard Herzberg, Molecular Spectra and Molecular Structure ,(1992)
M. Halmann, 530. Far-ultraviolet absorption spectra of phosphorus compounds in the gas phase Journal of the Chemical Society (Resumed). pp. 2853- 2856 ,(1963) , 10.1039/JR9630002853
Cyril Norman Hinshelwood, Bryan Topley, XLVII.—The unimolecular decomposition of phosphine Journal of The Chemical Society, Transactions. ,vol. 125, pp. 393- 406 ,(1924) , 10.1039/CT9242500393
S. Franchi, C. Pelosi, G. Attolini, Equilibrium calculations for VPE-InGaAsP Revue de Physique Appliquée. ,vol. 16, pp. 1- 4 ,(1981) , 10.1051/RPHYSAP:019810016010100