作者: Yasushi Hoshia , Hidetaka Nanaoa , Shigeyuki Moria
DOI:
关键词: Degradation (geology) 、 Decomposition 、 Chemical engineering 、 Hydrocarbon 、 Boundary layer 、 Materials science 、 Sulfide 、 Lubricant 、 Lubrication 、 Tin
摘要: Boundary lubricating behaviors were investigated from the viewpoint of surface chemistry based on our results. properties are closely related to chemical structure boundary films. TOF-SIMS (time flight secondary mass spectroscopy) which has several advantages such as high sensitivity, spatial resolution and was applied analysis Degradation films hard disk media by removal lubricant oil wear slider materials observed. It found that tribochemical degradation catalyzed material Al2O3 TiN. The suppressed when DLC c-BN used a material. Thin layer PTFE tribo-material composed PTFE-PEEK characterized TOFSIMS after lubrication tests with steel ring. coverage decreased increasing contact pressure 6 27 MPa welding occurred less than 20%. A tracer method stable isotopes 2 H(D), 13 C 18 O introduced for characterization formed organic additives. Effectiveness chemisorbed ethyl alcohol-d5 (CD3CD2OH) CrN alcohol confirmed analysis. An important role nascent surfaces reactions form layers investigated. For reaction EP additives, an sulfide more reactive phosphates. decomposition synthetic hydrocarbon under effect frictional heat.