Surface Chemical Aspects in Boundary Lubrication

作者: Yasushi Hoshia , Hidetaka Nanaoa , Shigeyuki Moria

DOI:

关键词: Degradation (geology)DecompositionChemical engineeringHydrocarbonBoundary layerMaterials scienceSulfideLubricantLubricationTin

摘要: Boundary lubricating behaviors were investigated from the viewpoint of surface chemistry based on our results. properties are closely related to chemical structure boundary films. TOF-SIMS (time flight secondary mass spectroscopy) which has several advantages such as high sensitivity, spatial resolution and was applied analysis Degradation films hard disk media by removal lubricant oil wear slider materials observed. It found that tribochemical degradation catalyzed material Al2O3 TiN. The suppressed when DLC c-BN used a material. Thin layer PTFE tribo-material composed PTFE-PEEK characterized TOFSIMS after lubrication tests with steel ring. coverage decreased increasing contact pressure 6 27 MPa welding occurred less than 20%. A tracer method stable isotopes 2 H(D), 13 C 18 O introduced for characterization formed organic additives. Effectiveness chemisorbed ethyl alcohol-d5 (CD3CD2OH) CrN alcohol confirmed analysis. An important role nascent surfaces reactions form layers investigated. For reaction EP additives, an sulfide more reactive phosphates. decomposition synthetic hydrocarbon under effect frictional heat.

参考文章(15)
Luis C Fernández-Torres, Byung-Il Kim, Scott S Perry, The Frictional Response of VC(100) Surfaces: Influence of 1-Octanol and 2,2,2-Trifluoroethanol Adsorption Tribology Letters. ,vol. 15, pp. 43- 50 ,(2003) , 10.1023/A:1023412122674
D. Philippon, M.-I. de Barros-Bouchet, T. L. Mogne, E. Gresser, J.-M. Martin, Experimental simulation of phosphites additives tribochemical reactions by gas phase lubrication Tribology - Materials, Surfaces & Interfaces. ,vol. 1, pp. 113- 123 ,(2007) , 10.1179/175158408X273586
Shigeyuki Mori, Mitsuru Suginoya, Yasukatsu Tamai, Chemisorption of Organic Compounds on a Clean Aluminum Surface Prepared by Cutting Under High Vacuum Tribology Transactions. ,vol. 25, pp. 261- 266 ,(1982) , 10.1080/05698198208983089
Shigeru Inami, Satoshi Takayanagi, Tomoo Kubo, Hidetaka Nanao, Ichiro Minami, Shigeyuki Mori, Effects of fine‐dispersed PTFE on load carrying capacity of PEEK Lubrication Science. ,vol. 20, pp. 299- 310 ,(2008) , 10.1002/LS.66
S. Mori, N. Onodera, M. Itoh, Tribochemical reactions of very thin layers on magnetic recording disks Wear. ,vol. 168, pp. 85- 90 ,(1993) , 10.1016/0043-1648(93)90201-V
Shigeyuki Mori, Masayuki Yoshida, Decomposition of Aromatic Compounds on Cut Nickel Surface Tribology Transactions. ,vol. 31, pp. 128- 132 ,(1988) , 10.1080/10402008808981808
Shigeyuki Mori, Yuji Shitara, Tribochemical activation of gold surface by scratching Applied Surface Science. ,vol. 78, pp. 269- 273 ,(1994) , 10.1016/0169-4332(94)90014-0
Tomoo Kubo, Renguo Lu, Hidetaka Nanao, Shigeyuki Mori, Kimihiro Kobayashi, Effect of Lubricant Additives on Tribochemical Decomposition of Hydrocarbon Oil on Nascent Steel Surfaces Bulletin of The Japan Petroleum Institute. ,vol. 53, pp. 55- 60 ,(2010)
F. Gao, P. V. Kotvis, D. Stacchiola, W. T. Tysoe, Reaction of tributyl phosphate with oxidized iron: surface chemistry and tribological significance Tribology Letters. ,vol. 18, pp. 377- 384 ,(2005) , 10.1007/S11249-004-2768-1