Dynamics of Ag + ions in Ag 2 S -doped superionic AgPO 3 glasses

作者: S. Bhattacharya , D. Dutta , A. Ghosh

DOI: 10.1103/PHYSREVB.73.104201

关键词: Ionic conductivityIonConductivityAtmospheric temperature rangeDopingInfraredAnalytical chemistryFourier transformActivation energyMaterials science

摘要: Dynamics of Ag + ions in 2 S-doped AgPO 3 glasses have been studied the frequency range 10 Hz to MHz and temperature 93-323 K. The composition dependence dc conductivity activation energy these has compared with that AgI-doped glasses. An attempt made explain comparatively lower for present S doped than by analyzing Fourier transform infrared data. frequency-dependent electrical data analyzed framework formalism. We obtained mobile ion concentration power-law exponent from analysis spectra. observed is independent primarily determined mobility. It also a fraction glass involved dynamic process. Scaling spectra be content compositions.

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