True Atomic-Resolution Imaging of (101̅4) Calcite in Aqueous Solution by Frequency Modulation Atomic Force Microscopy
作者： Sebastian Rode , Noriaki Oyabu , Kei Kobayashi , Hirofumi Yamada , Angelika Kühnle
DOI: 10.1021/LA803448V
关键词: Chemical physics 、 Carbonate 、 Dissolution 、 Adsorption 、 Biomineralization 、 Calcite 、 Oxygen 、 Aqueous solution 、 Chemistry 、 Kelvin probe force microscope 、 Analytical chemistry
摘要: Calcite (CaCO3) is one of the most abundant minerals on earth and plays an important role in a wide range different fields including, for example, biomineralization environmental geochemistry. Consequently, surface processes reactions such as dissolution growth well (macro)molecule adsorption are greatest interest both applied fundamental research. An in-depth understanding these requires knowledge about detailed structure its natural state which quite often liquid environment. We have studied stable cleavage plane calcite under conditions using frequency modulation atomic force microscopy. Using this technique, we achieved true atomic-resolution imaging, demonstrating high-resolution capability microscopy liquids. could reproduce contrast features reported before contact mode microscopy, originating from protruding oxygen atom carbonate gr...
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sci-hub.se 参考文章(24)
Grant S. Henderson, Alan L. Rachlin, M. Cynthia Goh, An atomic force microscope (AFM) study of the calcite cleavage plane: image averaging in Fourier space American Mineralogist. ,vol. 77, pp. 904- 910 ,(1992)
S.L.S. Stipp, C.M. Eggleston, B.S. Nielsen, Calcite surface structure observed at microtopographic and molecular scales with atomic force microscopy (AFM) Geochimica et Cosmochimica Acta. ,vol. 58, pp. 3023- 3033 ,(1994) , 10.1016/0016-7037(94)90176-7
P. Rahe, R. Bechstein, J. Schütte, F. Ostendorf, A. Kühnle, Repulsive interaction and contrast inversion in noncontact atomic force microscopy imaging of adsorbates Physical Review B. ,vol. 77, pp. 195410- ,(2008) , 10.1103/PHYSREVB.77.195410
Susan L. Stipp, Michael F. Hochella, Structure and bonding environments at the calcite surface as observed with X-ray photoelectron spectroscopy (XPS) and low energy electron diffraction (LEED) Geochimica et Cosmochimica Acta. ,vol. 55, pp. 1723- 1736 ,(1991) , 10.1016/0016-7037(91)90142-R
A.J. Gratz, P.E. Hillner, P.K. Hansma, Step dynamics and spiral growth on calcite Geochimica et Cosmochimica Acta. ,vol. 57, pp. 491- 495 ,(1993) , 10.1016/0016-7037(93)90449-7
C.A. Orme, A. Noy, A. Wierzbicki, M. T. McBride, M. Grantham, H.H. Teng, P.M. Dove, J.J. DeYoreo, Formation of chiral morphologies through selective binding of amino acids to calcite surface steps Nature. ,vol. 411, pp. 775- 779 ,(2001) , 10.1038/35081034
J. Rieger, J. Thieme, C. Schmidt, Study of Precipitation Reactions by X-ray Microscopy: CaCO3 Precipitation and the Effect of Polycarboxylates Langmuir. ,vol. 16, pp. 8300- 8305 ,(2000) , 10.1021/LA0004193
Lia Addadi, Steve Weiner, Crystals, asymmetry and life. Nature. ,vol. 411, pp. 753- 755 ,(2001) , 10.1038/35081227
R. M. Hazen, T. R. Filley, G. A. Goodfriend, Selective adsorption of L- and D-amino acids on calcite: Implications for biochemical homochirality Proceedings of the National Academy of Sciences of the United States of America. ,vol. 98, pp. 5487- 5490 ,(2001) , 10.1073/PNAS.101085998
Jeppe V Lauritsen, Adam S Foster, Georg H Olesen, Mona C Christensen, Angelika Kühnle, Stig Helveg, Jens R Rostrup-Nielsen, Bjerne S Clausen, Michael Reichling, Flemming Besenbacher, Chemical identification of point defects and adsorbates on a metal oxide surface by atomic force microscopy Nanotechnology. ,vol. 17, pp. 3436- 3441 ,(2006) , 10.1088/0957-4484/17/14/015