Macromonomers as polymeric intermediates. Synthesis and applications
作者： P. Rempp , E. Franta , P. Masson , P. Lutz
DOI: 10.1007/BFB0114484
关键词: Dispersity 、 Copolymer 、 Amphiphile 、 Polymer chemistry 、 Monomer 、 Chemistry 、 Polymerization 、 Ionic polymerization 、 Radical polymerization 、 Polymer
摘要: The methods developed for the synthesis of macromolecular monomers (macromonomers) are reviewed, with emphasis on those based ionic “living” polymerization techniques which give access to well-defined species low polydispersity. ability terminal unsaturation undergo free radical (or copolymerization a vinylic or acrylic monomer) is considered next. Homopolymacromonomers characterized by an unusually large segment density within polymer coil. chief interest macromonomers easy graft copolymers they can provide, especially amphiphilic constituted hydrophobic backbone carrying hydrophilic grafts. Further applications also be envisioned.
springer.com
sci-hub.se 参考文章(19)
Paul F. Rempp, Emile Franta, Macromonomers: Synthesis, characterization and applications Springer, Berlin, Heidelberg. pp. 1- 53 ,(1984) , 10.1007/3-540-12793-3_6
Bernard Boutevin, Yves Piétrasanta, Mohamed Taha, Tarek El Sarraf, Synthèse de macromères à base de chlorures de vinyle et de vinylidène au moyen de télomères Macromolecular Chemistry and Physics. ,vol. 184, pp. 2401- 2407 ,(1983) , 10.1002/MACP.1983.021841201
Takao Nishimura, Mizuo Maeda, Yoshiaki Nitadori, Teiji Tsuruta, Synthesis and copolymerization of a polyamine macromer: Molecular design of a new functional graft copolymer Macromolecular Chemistry and Physics. ,vol. 183, pp. 29- 45 ,(1982) , 10.1002/MACP.1982.021830103
K. F. Gillman, E. Senogles, Graft copolymers with short side chains Journal of Polymer Science Part B: Polymer Letters. ,vol. 5, pp. 477- 481 ,(1967) , 10.1002/POL.1967.110050608
Joseph P. Kennedy, Suhas C. Guhaniyogi, Virgil Percec, New telechelic polymers and sequential copolymers by polyfunctional initiator-transfer agents (Inifers): 28. Glycidyl ethers of bisphenol- and trisphenol-PIB and their curing to epoxy resins Polymer Bulletin. ,vol. 8, pp. 571- 578 ,(1982) , 10.1007/BF00262937
J.P. Kennedy, C.Y. Lo, Macromers by carbocationic polymerization Polymer Bulletin. ,vol. 8, pp. 63- 67 ,(1982) , 10.1007/BF00263009
EricJ. Goethals, MarcA. Vlegels, Synthesis of a polyamine macromer by cationic polymerization Polymer Bulletin. ,vol. 4, pp. 521- 525 ,(1981) , 10.1007/BF00284064
A. Revillon, T. Hamaide, Macromer copolymerization reactivity ratio determined by GPC analysis Polymer Bulletin. ,vol. 6, pp. 235- 241 ,(1982) , 10.1007/BF00255392
Paul Rempp, Pierre Lutz, Patrick Masson, Emile Franta, Macromonomers ‐ a new class of polymeric intermediates in macromolecular synthesis. I ‐ synthesis and characterization Macromolecular Chemistry and Physics. ,vol. 8, pp. 3- 15 ,(1984) , 10.1002/MACP.1984.020081984102
C. H. Bamford, E. F. T. White, The preparation of block copolymers by the tertiary base method Transactions of the Faraday Society. ,vol. 54, pp. 268- 277 ,(1958) , 10.1039/TF9585400268