Redox reactions of metal carbonyls of group 5A
作者： Fausto Calderazzo , Guido Pampaloni
DOI: 10.1039/C39840001249
关键词: Oxidation reduction 、 Medicinal chemistry 、 Cobaltocene 、 Group (periodic table) 、 Oxidizing agent 、 Chemistry 、 Acetylacetone 、 Diketone 、 Redox 、 Inorganic chemistry 、 Metal carbonyl
摘要: Redox reaction of V(CO)6 with [Co(CO)4]–, [Mn(CO)5]–, [M2(CO)10]2–, or [M(η5-C5H5)(CO)3]–(M = Cr, Mo, W), Co(η5-C5H5)2 occur rapidly at 25 °C and lower in hydrocarbons; on the other hand, is oxidized to V(η5-C5H5)(CO)4 by Mn(η5-C5H5)2 Ni(η5-C5H5)2 two-electron oxidation [Nb(CO)6]– [Nb2X3(CO)8]–anion (X Cl, Br, I, acetylacetonato), can be carried out using a number oxidizing agents (HgII,CUII,CUIAgI, FeIII).
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