Carbon–hydrogen activation chemistry: hydroxylation of C2, C3, and cyclo-C6 hydrocarbons by manganese cluster catalysts with a mono-oxygen transfer reagent
作者： Richard H. Fish , Raymond H. Fong , John B. Vincent , George Christou
DOI: 10.1039/C39880001504
关键词: Chemistry 、 Cyclohexanol 、 Hydrocarbon 、 Reagent 、 Pyridine 、 Manganese 、 Medicinal chemistry 、 Hydroxylation 、 Organic chemistry 、 Catalysis 、 Aliphatic compound
摘要: Manganese clusters, Mn3–4O1–2LxLy(Lx= RCO2–; Ly= pyridine or 2,2′-bipyridine), are novel catalysts that can convert C–H bonds to C–OH in C2, C3, and cyclo-C6 hydrocarbons the presence of t-butyl hydroperoxide as mono-oxygen transfer reagent.
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