The general failure of Kleinman symmetry in practical nonlinear optical applications

作者: Christopher A. Dailey , Brian J. Burke , Garth J. Simpson

DOI: 10.1016/J.CPLETT.2004.03.109

关键词: Range (mathematics)Simple (abstract algebra)PhysicsNonlinear opticalPermutationMolecular symmetryClassical mechanicsSymmetry (physics)Dispersion relation

摘要: Abstract Evidence is presented to refute the general applicability of overall permutation symmetry condition originally proposed by Kleinman in describing non-resonant nonlinear optical properties overwhelming majority practical materials and systems. Kramers–Kronig dispersion relations demonstrate that range validity substantially more restrictive than widely assumed. These findings are supported numerous experimental observations effects explicitly forbidden but allowed relations. Considerations molecular coupled with yield alternative simple macroscopic consistent observations.

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