THE RADIOLYSIS OF DILUTE SOLUTIONS OF LYSOZYME. I. ENZYMATIC STUDIES RELATING TO THE OXYGEN EFFECT.
作者： Robert J. Shalek
DOI: 10.1080/09553006814550731
关键词: Radiolysis 、 Enzyme 、 Chemistry 、 Lysozyme 、 Inorganic chemistry 、 Cysteine 、 Oxygen 、 Reaction rate constant
摘要: SummaryPulse radiolysis was used for the study of transients formed from lysozyme solutions. Reactions these with cysteine and oxygen were analysed kinetically. The rate constant reaction e−aq 5·2 × 1010 M−1 sec−1 OH 3·1 sec−1. For transient (λmax 400 mμ) oxygen, constants 4·1 106 3·38 108 respectively. corresponding figures 310 4·6 1·6 These data are correlated those obtained steady-state elucidate an aspect known radiobiological effect.
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