New insights into secondary gas generation from the thermal cracking of oil: Methylated monoaromatics. A kinetic approach using 1,2,4-trimethylbenzene. Part III: An isotopic fractionation model
作者： Luc Fusetti , Françoise Behar , Roda Bounaceur , Paul-Marie Marquaire , Kliti Grice
DOI: 10.1016/J.ORGGEOCHEM.2009.10.013
关键词: Kinetics 、 Activation energy 、 Physical chemistry 、 Thermal stability 、 Toluene 、 Xylene 、 Yield (chemistry) 、 Condensation reaction 、 Organic chemistry 、 Chemistry 、 1,2,4-Trimethylbenzene
摘要: … NSO compounds and aromatic hydrocarbons are indeed more gas prone under geological conditions (eg Behar et al., 2008a). However, the high molecular weight of the NSO fraction …
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J. G. Erdman, J. E. Smith, D. A. Morris, Migration, Accumulation and Retention of Petroleum in the Earth 8th World Petroleum Congress. ,(1971)
U. Brand, H. Hippler, L. Lindemann, J. Troe, Carbon-carbon and carbon-hydrogen bond splits of laser-excited aromatic molecules. 1. Specific and thermally averaged rate constants The Journal of Physical Chemistry. ,vol. 94, pp. 6305- 6316 ,(1990) , 10.1021/J100379A030
Yu-Ran Luo, Handbook of Bond Dissociation Energies in Organic Compounds ,(2002)
Frédéric Lannuzel, Influence des aromatiques sur la stabilité thermique des pétroles dans les gisements Institut National Polytechnique de Lorraine - INPL. ,(2007)
Dietrich H. Welte, Bernard P. Tissot, Petroleum Formation and Occurrence ,(1989)
R. Kee, F. Rupley, J. Miller, Chemkin-II : A Fortran Chemical Kinetics Package for the Analysis of Gas Phase Chemical Kinetics Sandia Report, SAND89-8009B. ,(1989) , 10.2172/5681118
R. S. Zhu, Z. F. Xu, M. C. Lin, Ab initio studies of alkyl radical reactions: Combination and disproportionation reactions of CH3 with C2H5, and the decomposition of chemically activated C3H8 Journal of Chemical Physics. ,vol. 120, pp. 6566- 6573 ,(2004) , 10.1063/1.1665370
Wallace G. Dow, Leslie B. Magoon, The Petroleum System: From Source to Trap ,(1994)
M. Szwarc, The C–H Bond Energy in Toluene and Xylenes The Journal of Chemical Physics. ,vol. 16, pp. 128- 136 ,(1948) , 10.1063/1.1746794
H. Hippler, S. Seisel, J. Troe, Pyrolysis of p-xylene and of 4-methylbenzyl radicals Symposium (International) on Combustion. ,vol. 25, pp. 875- 882 ,(1994) , 10.1016/S0082-0784(06)80722-8