Tunable Porosity of Cross-Linked-Polyhedral Oligomeric Silsesquioxane Supports for Palladium-Catalyzed Aerobic Alcohol Oxidation in Water

作者: Preeyanuch Sangtrirutnugul , Thanawat Chaiprasert , Warodom Hunsiri , Thanudkit Jitjaroendee , Patsaya Songkhum

DOI: 10.1021/ACSAMI.7B03910

关键词: Amorphous solidPalladiumPolymer chemistryMesoporous materialSilsesquioxaneBET theoryMaterials scienceRadical polymerizationNuclear chemistryPorosityAlcohol oxidation

摘要: Polyhedral oligomeric silsesquioxane (POSS)-based materials, poly-POSS-T n [n= 8 (1), 10 (2), 12 (3), and mix (4)], were prepared in high yields via free radical polymerization of …

参考文章(62)
Matthias Thommes, Katsumi Kaneko, Alexander V. Neimark, James P. Olivier, Francisco Rodriguez-Reinoso, Jean Rouquerol, Kenneth S.W. Sing, Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) Pure and Applied Chemistry. ,vol. 87, pp. 1051- 1069 ,(2015) , 10.1515/PAC-2014-1117
Yace Mi, Weiqing Zhou, Qiang Li, Donglai Zhang, Rongyue Zhang, Guanghui Ma, Zhiguo Su, Detailed exploration of structure formation of an epoxy-based monolith with three-dimensional bicontinuous structure RSC Advances. ,vol. 5, pp. 55419- 55427 ,(2015) , 10.1039/C5RA08549G
R. Rahul, R. K. Singh, B. Bera, R. Devivaraprasad, M. Neergat, The role of surface oxygenated-species and adsorbed hydrogen in the oxygen reduction reaction (ORR) mechanism and product selectivity on Pd-based catalysts in acid media. Physical Chemistry Chemical Physics. ,vol. 17, pp. 15146- 15155 ,(2015) , 10.1039/C5CP00692A
Nirmalya Moitra, Kazuyoshi Kanamori, Yumi H Ikuhara, Xiang Gao, Yang Zhu, George Hasegawa, Kazuyuki Takeda, Toyoshi Shimada, Kazuki Nakanishi, None, Reduction on reactive pore surfaces as a versatile approach to synthesize monolith-supported metal alloy nanoparticles and their catalytic applications Journal of Materials Chemistry A. ,vol. 2, pp. 12535- 12544 ,(2014) , 10.1039/C4TA01767F
Sonia E. Létant, Amitesh Maiti, Ticora V. Jones, Julie L. Herberg, Robert S. Maxwell, Andrew P. Saab, Polyhedral Oligomeric Silsesquioxane (POSS)-Stabilized Pd Nanoparticles: Factors Governing Crystallite Morphology and Secondary Aggregate Structure Journal of Physical Chemistry C. ,vol. 113, pp. 19424- 19431 ,(2009) , 10.1021/JP903866F
Yan Leng, Jian Liu, Chenjun Zhang, Pingping Jiang, A polyhedral oligomeric silsesquioxane (POSS)-bridged oxo-molybdenum Schiff base complex with enhanced heterogeneous catalytic activity in epoxidation Catalysis Science & Technology. ,vol. 4, pp. 997- 1004 ,(2014) , 10.1039/C3CY01014G
Cyril Aymonier, Denis Bortzmeyer, Ralf Thomann, Rolf Mülhaupt, Poly(Methyl methacrylate)/Palladium Nanocomposites: Synthesis and Characterization of the Morphological, Thermomechanical, and Thermal Properties Chemistry of Materials. ,vol. 15, pp. 4874- 4878 ,(2003) , 10.1021/CM031049H