Dislocation-Driven Nanowire Growth and Eshelby Twist

作者: M. J. Bierman , Y. K. A. Lau , A. V. Kvit , A. L. Schmitt , S. Jin

DOI: 10.1126/SCIENCE.1157131

关键词: NanowireDislocationCrystallographyVapor–liquid–solid methodCondensed matter physicsMaterials scienceCharacterization (materials science)Crystal growthBurgers vectorNanostructureLead sulfide

摘要: Hierarchical nanostructures of lead sulfide nanowires resembling pine trees were synthesized by chemical vapor deposition. Structural characterization revealed a screwlike dislocation in the nanowire trunks with helically rotating epitaxial branch nanowires. It is suggested that the screw component of an axial dislocation provides the self-perpetuating steps to enable one-dimensional crystal growth, in contrast to mechanisms that require metal catalysts. The rotating trunks and branches are the consequence of the Eshelby twist …

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