作者: Yuya Yamashita , Koichi Ito , Haruki Mizuno , Keisuke Okada
关键词: Macromonomer 、 Styrene 、 Polystyrene 、 Methacrylate 、 Glycidyl methacrylate 、 Polymerization 、 Organic chemistry 、 Chemistry 、 Copolymer 、 Comonomer 、 Polymer chemistry
摘要: Graftcopolymers of well-defined structure and composition were prepared by the radical copolymerization polystyrene macromonomers with functional comonomers. The macromonomer was polymerization styrene in presence monoiodoacetic acid as a chain transfer agent, followed an end-capping reaction glycidyl methacrylate. In case 2-hydroxyethyl methacrylate comonomer, hydrophilic graftcopolymer soluble polar solvent obtained characterized thin layer chromatography. perfluoroalkyl acrylate hydrophobic ordinary obtained.