Enhanced Basicity of Ag2O by Coordination to Soft Anions
作者： Bo Ren , Meiyan Wang , Jingyao Liu , Jiantao Ge , Hai Dong
关键词: Catalysis 、 Iodide 、 Electrophile 、 Metal 、 Reactivity (chemistry) 、 Photochemistry 、 Chemistry 、 Bromide 、 Transesterification reaction 、 Inorganic chemistry
摘要: In Ag2O-mediated benzylation, the addition of a catalytic amount KI can greatly improve reactivity. This is usually attributed to formation more reactive iodo-substituted electrophile. However, our studies show this be due enhanced basicity Ag2O through coordination soft iodide anions silver atom, and an initiator. A NaBr catalyze transesterification reactions, indicating by bromide. We believe that general effect for metal oxides anions, applicable wider range organic reaction systems.
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