C70 Fullerene Catalyzed Photoinduced Aerobic Oxidation of Benzylamines to Imines and Aldehydes.
作者： Inder Kumar , Rakesh Kumar , Shiv Shankar Gupta , Upendra Sharma , None
关键词: Photochemistry 、 Substrate (chemistry) 、 Imine 、 Density functional theory 、 Photocatalysis 、 Chemistry 、 C70 fullerene 、 Catalysis 、 Function group 、 Amine gas treating
摘要: C70 fullerene catalyzed photoinduced oxidation of benzylic amines at ambient conditions has been explored here. The developed strategy's main feature includes the additive/oxidant-free conversion amine to corresponding imine and aldehydes. reaction manifests broad substrate scope with excellent function group leniency is applicable up gram scale. Further, symmetrical secondary can also be synthesized from in a one-pot two-step process. Various experiments density functional theory studies revealed that current involves generation reactive oxygen species, single electron transfer reaction, benzyl radical formation as key steps under photocatalytic conditions.
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