Aerobic oxidation of benzyl alcohols by MoVI compounds
作者： Kandasamy Jeyakumar , Dillip Kumar Chand
DOI: 10.1002/AOC.1141
关键词:
摘要: Selective and controlled aerobic oxidation of activated benzyl alcohols to the corresponding aldehydes is achieved in refluxing CH3CN using catalytic amounts MoO2Cl2(L)2 where L DMSO, DMF or THF. The catalysis reactions are possible under open air absence any other external co-oxidants. However, bubbling oxygen reaction mixture useful making sustained. Both deactivated varieties α-substituted (secondary alcohols) give ketones same conditions. inexpensive catalyst selective towards primary also, being mild, stops at aldehyde stage, it synthetically useful. Copyright © 2006 John Wiley & Sons, Ltd.
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