Preparation method of bis(PEPA) phenylphosphonate compound
作者： 俞春雷 , 韩志慧 , 郑琦 , 董荣
DOI:
关键词: Yield (chemistry) 、 Salt (chemistry) 、 Fire retardant 、 Polyester 、 PEPA 、 Chemistry 、 Selectivity 、 Organic chemistry 、 Polypropylene 、 Hydrogen chloride
摘要: The invention relates to a preparation method of bis(PEPA) phenylphosphonate compound. This compound has structural formula shown as below, and the comprises: in an organic solvent, reacting phenyl phenylphosphonic dichloride with PEPA sodium salt or zinc salt, purifying obtain white solid, phenylphosphonate. product is useful flame retardant for materials such polyester PBT, PET, polypropylene PP polyester. simple process, reaction time short, conditions are mild, selectivity good, yield high, no hydrogen chloride pollution occurs, separating easy, equipment corrosion low, investment easy large-scale production.
参考文章(2)
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Hua-Qiao Peng, Qian Zhou, De-Yi Wang, Li Chen, Yu-Zhong Wang, A novel charring agent containing caged bicyclic phosphate and its application in intumescent flame retardant polypropylene systems Journal of Industrial and Engineering Chemistry. ,vol. 14, pp. 589- 595 ,(2008) , 10.1016/J.JIEC.2008.05.011