Insertion of Carbodiimides and Organic Azides into Actinide−Carbon Bonds
作者： William J. Evans , Justin R. Walensky , Joseph W. Ziller , Arnold L. Rheingold
DOI: 10.1021/OM900135E
关键词: Actinide 、 Crowding in 、 Organic chemistry 、 Carbon 、 Chemistry 、 Alkyl 、 Steric effects
摘要: Manipulation of steric crowding in organoactinide complexes has been explored by examining the insertion chemistry carbodiimides, RN═C═NR, and organic azides, RN3, with actinide alkyl, alkynyl, ...
acs.org
core.ac.uk 
sci-hub.se 参考文章(71)
Michael Wedler, Mathias Noltemeyer, Frank T. Edelmann, The Synthesis and Structure of an Unusual Uranium Pentachloride Derivative Angewandte Chemie. ,vol. 31, pp. 72- 73 ,(1992) , 10.1002/ANIE.199200721
Eric J. Schelter, David E. Morris, Brian L. Scott, Jaqueline L. Kiplinger, Actinide-mediated coupling of 4-fluorobenzonitrile: synthesis of an eight-membered thorium(IV) tetraazametallacycle. Chemical Communications. pp. 1029- 1031 ,(2007) , 10.1039/B614050E
Nonsee Nimitsiriwat, Vernon C. Gibson, Edward L. Marshall, Pittaya Takolpuckdee, Atanas K. Tomov, Andrew J. P. White, David J. Williams, Mark R. J. Elsegood, Sophie H. Dale, Mono- versus bis-chelate formation in triazenide and amidinate complexes of magnesium and zinc. Inorganic Chemistry. ,vol. 46, pp. 9988- 9997 ,(2007) , 10.1021/IC701061Q
Xinmin Yang, Wayne A. King, Michal Sabat, Tobin J. Marks, Cationic actinide metallocene alkyls and hydrides. Metal bis(dicarbollides) as counterions Organometallics. ,vol. 12, pp. 4254- 4258 ,(1993) , 10.1021/OM00034A079
Zerong Lin, Jean Francois Le Marechal, Michal Sabat, Tobin J. Marks, Models for organometallic molecule-support complexes. Synthesis and properties of cationic organoactinides Journal of the American Chemical Society. ,vol. 109, pp. 4127- 4129 ,(1987) , 10.1021/JA00247A056
Jie Zhang, Ruan, Shao, Cai, Weng, Zhou, Insertion of Carbodiimide into the Ln−C σ-Bond of Organolanthanide Complexes. Synthesis, Reaction, and Characterization of Organolanthanide Amidinates (C5H5)2Ln[tBuNC(nBu)NtBu] (Ln = Er, Gd, Y) Organometallics. ,vol. 21, pp. 1420- 1424 ,(2002) , 10.1021/OM0109859
Thibault Cantat, Christopher R. Graves, Kimberly C. Jantunen, Carol J. Burns, Brian L. Scott, Eric J. Schelter, David E. Morris, P. Jeffrey Hay, Jaqueline L. Kiplinger, Evidence for the involvement of 5f orbitals in the bonding and reactivity of organometallic actinide compounds: thorium(IV) and uranium(IV) bis(hydrazonato) complexes. Journal of the American Chemical Society. ,vol. 130, pp. 17537- 17551 ,(2008) , 10.1021/JA8067287
A. Dormond, A. Aaliti, A. Elbouadili, C. Moise, Réactivité des liaisons σ uranium-carbone: réactions du méthyltris(hexaméthyldisilylamido)uranium Journal of Organometallic Chemistry. ,vol. 329, pp. 187- 199 ,(1987) , 10.1016/S0022-328X(00)99792-4
Yingming Yao, Yunjie Luo, Jinglei Chen, Zhenqin Zhang, Yong Zhang, Qi Shen, Synthesis and characterization of bis(guanidinate)lanthanide diisopropylamido complexes: New highly active initiators for the polymerizations of ε-caprolactone and methyl methacrylate Journal of Organometallic Chemistry. ,vol. 679, pp. 229- 237 ,(2003) , 10.1016/S0022-328X(03)00600-4
Claude Villiers, Pierre Thuéry, Michel Ephritikhine, A Comparison of Analogous 4f- and 5f-Element Compounds: Syntheses, X-ray Crystal Structures and Catalytic Activity of the Homoleptic Amidinate Complexes [M{MeC(NCy)2}3] (M = La, Nd or U) European Journal of Inorganic Chemistry. ,vol. 2004, pp. 4624- 4632 ,(2004) , 10.1002/EJIC.200400491