Desorption behaviour of polychlorinated dibenzo-p-dioxins/dibenzofurans on a packed fly ash bed
作者： Ruud Addink , Harrie A.J. Govers , Kees Olie
DOI: 10.1016/0045-6535(95)00266-B
关键词: Dibenzofuran 、 Activation energy 、 Environmental chemistry 、 Fly ash 、 Polychlorinated dibenzofurans 、 Incineration 、 Polychlorinated Dibenzo-p-dioxins 、 Chemistry 、 Desorption
摘要: Abstract When incinerator fly ash is heated at 398 °C under a stream of N 2 O polychlorinated dibenzo-p-dioxin (PCDD) and dibenzofuran (PCDF) concentrations are lowered. Dechlorination/dtx;omposition desorption competing processes. In this paper the was studied: within PCDD/F homologues, all isomers desorb an equal rate. Obviously, values activation energy from surface (ΔG#398,des do not differ significantly between these isomers.
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sci-hub.se 参考文章(11)
Mirjam H. Schoonenboom, Paulus N. Smit, Kees Olie, Alumina as a model support in the formation and dechlorination of polychlorinated dibenzo-p-dioxins and dibenzofurans Chemosphere. ,vol. 25, pp. 1897- 1906 ,(1992) , 10.1016/0045-6535(92)90029-Q
Jan G. P. Born, Peter Mulder, Robert Louw, Fly ash mediated reactions of phenol and monochlorophenols: oxychlorination, deep oxidation, and condensation Environmental Science & Technology. ,vol. 27, pp. 1849- 1863 ,(1993) , 10.1021/ES00046A013
K. Olie, P.L. Vermeulen, O. Hutzinger, Chlorodibenzo-p-dioxins and chlorodibenzofurans are trace components of fly ash and flue gas of some municipal incinerators in The Netherlands Chemosphere. ,vol. 6, pp. 455- 459 ,(1977) , 10.1016/0045-6535(77)90035-2
Carolyn J. Koester, Ronald A. Hites, Calculated physical properties of polychlorinated dibenzo-p-dioxins and dibenzofurans Chemosphere. ,vol. 17, pp. 2355- 2362 ,(1988) , 10.1016/0045-6535(88)90146-4
Elmar R. Altwicker, Some laboratory experimental designs for obtaining dynamic property data on dioxins Science of The Total Environment. ,vol. 104, pp. 47- 72 ,(1991) , 10.1016/0048-9697(91)90007-2
G.A. Junk, C.S. Ford, A review of organic emissions from selected combustion processes Chemosphere. ,vol. 9, pp. 187- 230 ,(1980) , 10.1016/0045-6535(80)90079-X
Michael S. Milligan, Elmar Altwicker, The relationship between de novo synthesis of polychlorinated dibenzo-p-dioxins and dibenzofurans and low-temperature carbon gasification in fly ash Environmental Science & Technology. ,vol. 27, pp. 1595- 1601 ,(1993) , 10.1021/ES00045A015
H. Vogg, L. Stieglitz, Thermal behavior of PCDD/PCDF in fly ash from municipal incinerators Chemosphere. ,vol. 15, pp. 1373- 1378 ,(1986) , 10.1016/0045-6535(86)90412-1
H VOGG, M METZGER, L STIEGLITZ, Recent Findings On the Formation and Decomposition of PCDD/PCDF in Municipal Solid Waste Incineration: Waste Management & Research. ,vol. 5, pp. 285- 294 ,(1987) , 10.1016/0734-242X(87)90080-2
L. C. Dickson, M. Hutzinger, F. W. Karasek, V. Ozvacic, Determination of Desorption Losses of Polychlorinated Dibenzo-p-Dioxins from Municipal Incinerator Flyash by Gas Chromatography/Mass Spectrometry International Journal of Environmental Analytical Chemistry. ,vol. 24, pp. 55- 74 ,(1986) , 10.1080/03067318608076459